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Aldrich ChemFiles 2005, 5.4, 7.

Aldrich ChemFiles 2005, 5.4, 7.


These chiral imine-ligands have recently been used in the vanadium-catalyzed oxidation of sulfides in conjunction with hydrogen peroxide. Optically active sulfoxides are obtained in high yields and enantioselectivities (Scheme 16).1

Scheme 16

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  1. Pellotier, B. et al. Synlett 2002, 1055.

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