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Organic and Printed Electronics

High Efficiency Sensors

Ru(d8-bipy3)PF6 is known to be an excellent candidate for emissive materials in organic light-emitting diodes (OLEDs) and organic light-emitting electrochemical cells (OLEC) for sensor applications1. Quantum efficiencies of these materials are in the range of 1.2-1.5%. Scientists at Sigma-Aldrich® are aware of the improvement in emission lifetimes of triplet emitting compounds by deuterating the organic ligand. The deuterated material shows a 20-25% increase in emission lifetime compared to the undeuterated material as shown below2. We think that you will find our newest material Ru(d8-bipy3)PF6 will improve your sensor efficiency.

652407

652407

Emission Lifetimes3

Matrix Temp. Ru(bpy3) Ru(d8-bpy3)
Water 298K 610ns 760ns
Crystal 5K 64ms 80ms

 

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References:

  1. Rudman, H.; Rubner, M.F. J. Appl. Phys. 2001, 90, 4338.
  2. Browne, W.R.; Vos, J.G. Coord. Chem. Rev., 2001, 219, 761.
  3. Krausz, E.; Moran, G.; Riesen, H. Chem. Phys. Lett. 1990, 165, 401.
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