Organic and Printed Electronics

PCBM-Based n-Type Semiconductors

Unique chemistry and physics of fullerene (C60) materials continue to stimulate advances in applied and fundamental science. Fullerenes are known as excellent electron acceptors and can be chemically modified to improve solubility in organic solvents. Such soluble fullerene derivatives are known as some of the best n-type organic semiconductors1. Moreover, molecular heterojunctions made by covalently linking fullerenes with electron donating or photoactive macromolecules show promise as intrinsic p/n-type semiconductors and even artificial mimics of biological photosynthesis.2 To help our customers achieve their research breakthroughs in organic electronics, Sigma-Aldrich® is pleased to offer a line of high quality functionalized fullerene products.

Methanofullerene Phenyl-C61-Butyric-Acid-Methyl-Ester ([60]PCBM) is an effective solution processable n-type organic semiconductor. It can be blended with p-type conjugated polymers to make photovoltaic (PV) cells3,4 and thin-film organic field effect transistors (OFETs),5 and has also shown promise for use in photodectors.6 [60]PCBM is soluble in the same organic solvents as excellent p-type semiconductors such as: MDMO-PPV, MEH-PPV and P3HT (Table 1). This simplifies the preparation of blends and solution processing of heterojuction PV cells and OFETs. The high affinity of PCBM results is efficient photo-induced electron transfer from p-type polymers as well as from metal electrodes in biased thin-film OFETs.7 Power conversion efficiencies of up to ~4.4% have been reported for bulk heterojunction PV cells made with [60]PCBM.8

Table 1: Conduction (LUMO) and valence (HOMO) band energies of p- and n-type organic semiconductors available from Sigma-Aldrich4,5.

Organic Semiconductor
Product No.
Soluble in:



(MW 40 – 70 kDa)

(MW 70 – 100 kDa)

(MW 150 – 250 kDa)


(electronic grade)

The fabrication of thin film organic electronics devices is complex, with slight variations of molecular structures having profound effects on film morphology and charge transport. To help you optimize the performance of your devices, Sigma-Aldrich is pleased to offer a library of PCBMs that includes [60]PCBM analogs based on higher fullerenes (C70 and C84), as well as those derived by chemical alterations of the addend moeiety to vary solubility and electronic properties. Members of the library have shown advantages in different devices and will help you explore and experiment in your research. Different purity grades of [60]PCBM are available for device scale-up, research, and exploratory work. Tables 2 and 3 below provide application, properties and product information to help you select the PCBMs for your applications.

Table 2:
Sigma-Aldrich PCBM Library

Prod. No.

Product Name



Add to Cart
684430 Phenyl-C61-Butyric-Acid-Methyl Ester, [60]PCBM,
99% (scale-up grade)

Best-known PCBM compound. Effective n-type semiconductor soluble in organic solvents. Used for solar cells (OPVs), thin-film transistors (OFETs), and photodetectors.6,10-11
684449 Phenyl-C61-Butyric-Acid-Methyl Ester, [60]PCBM,
99.5% (research grade)

684457 Phenyl-C61-Butyric-Acid-Methyl Ester, [60]PCBM,
99.9% (for exploratory work)

684465 Phenyl-C71-Butyric-Acid-Methyl Ester, [70]PCBM, 99% [70]PCBM has increased optical absorption in the visible region compared to [60PCBM. This can lead to improved light-harvesting in OPVs,12 especially in combination with large bandgap donors like MDMO-PPV (546461)
684473 Phenyl-C85-Butyric-Acid-Methyl Ester, [84]PCBM, 99% [84]PCBM has the strongest visible absorption and highest electron accepting ability of available PCBMs. Very low LUMO makes [84]PCBM a promising material for OFETs.13
685321 Phenyl-C61-Butyric-Acid-Butyl Ester, PCBB, [60]PCB-C4> 97% PCBB is slightly more soluble than [60]PCBM, resulting in improved film morphology and higher performing OPV devices deposited from certain organic solvents (THF, p-xylene).14
684481 Phenyl-C61-Butyric-Acid-Octyl Ester, PCBO, [60]PCB-C8 , 99% Highly soluble PCBM suitable for applications as a general electron acceptor and scavenger in organic solvents and blends.
688215 Thienyl-C61-Butyric-Acid-Methyl Ester, [60]ThCBM, 99% PCBM derivative optimized for optimal blending with polythiophene p-type semiconductors, such as P3HT (669067).15
684503 Pentadeuterophenyl-C61-Butyric-Acid-Methyl Ester, d5-PCBM, 99%

Isotopically labeled PCBM for spectroscopic (e.g. SIMS) studies of film morphology and diffusion in thin-film organic devices.

Table 3:
  Properties of selected PCBMs *

Product [60]PCBM [70]PCBM [84]PCBM [60]ThCBM
Product Number 684430
684465 684473 688215
First Reduction Potential, E1/2 (V)  -1.078  -1.089  -0.730  -1.08
Solubility (mg/ml)
 · toluene
 · p-xylene
 · chlorobenzene
 · chloroform
 · o-dichlorobenzene (ODCB)

Molar Extinction Coefficients
(mol-1 cm-1)
400 nm
650 nm



* From Kronholm, D.; Hummelen, J. Material Matters 2007, Vol. 2 No. 3.


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