GC Analysis of Sulfur Compounds in Gasoline on SPB®-1 SULFUR

GC Analysis of Sulfur Compounds in Gasoline on SPB®-1 SULFUR

Conditions

column SPB-1 SULFUR, 30 m x 0.32 mm I.D., 4.0 µm (24158)
oven 35 ºC, 5 ºC/min to 200 ºC
carrier gas helium, 20 cm/sec
sample Gasoline
injection 1 µL100:1 split
inj. temp. 275 °C
detector FID, 300 ºC; FPD, 300 ºC

Description

Analysis Note Two issues must be overcome for the analysis of sulfur compounds in fuels. 1) Detection of these compounds in a hydrocarbon sample matrix, and 2) adsorption of these compounds by the column. Sulfur specific detectors, such as a flame photometric detector (FPD), can be used to overcome the first challenge. A low phase ratio column, such as the SPB-1 SULFUR, can be used to overcome the second challenge. This slide shows the analysis of a gasoline sample, in which the column effluent was split to two detectors. The top chromatogram shows the FID response, and the bottom chromatogram shows the FPD response.
Categories Analytical Chromatography, GC Applications, Sulfur Compounds
Featured Industry Petroleum
Legal Information SPB is a registered trademark of Sigma-Aldrich Co. LLC
Other Notes Complementary products:
Syringes
Vials
Gas Purification and Gas Management
Inlet Liners, Glass Wool, and Specialized Hand Tools
Septa and Specialized Hand Tools
Column Ferrules, Nuts, and Specialized Hand Tools
suitability application for GC

Materials

     
Related Links