Analytical Method: Vanadium in water

Intstruments and Reagents:

Cat.No. 173016  Spectroquant® VIS Spectrophotometer Prove 100 or

Cat.No. 173017  Spectroquant® UV/VIS Spectrophotometer Prove 300 or

Cat.No. 173018  Spectroquant® UV/VIS Spectrophotometer Prove 600 or
Cat.No. 104936  Potassium chloride for analysis
Cat.No. 109057  Hydrochloric acid 1 mol/l
Cat.No. 100983  Ethanol for analysis
Cat.No. 116754  Water for analysis
Aldrich Cat.No. T 3,261-1 2-Thiophen-carboxylic hydrazide
Membrane filter 0.45 μm pore diameter
 
Reagent 1:
Dissolve 6 g 2-thiophen-carboxylic hydrazide in 40 ml ethanol.
 
Reagent 2:
Place 12.5 ml potassium chloride solution, 0.2 mol/l and 3.25 ml hydrochloric acid, 0.2 mol/l in a 50-ml volumetric flask and make up to the mark with water.
 
Measurement range:
0.50 - 5.00 mg/l V at cell length 10 mm and 405 nm
 
Sample preparation:
The sample solution must be clear; if not, filter through a folded filter or membrane filter with 0.45 μm pore diameter.

 
Analysis:
Mix 10.0 ml of sample solution, 0.25 ml reagent 1, 0.30 ml reagent 2 in a test tube. Measure against water at 405 nm.

Parameter list for programming the photometer Spectroquant® Prove 100, Prove 300 and Prove 600

Method-designation Vanadium
Units mg/l
Citation V
Wavelength 405 nm
Cell 10 mm
Resolution 0.01
Meas. range 0.50 - 5.00
User range user defined
Zero point (E0) 0.000
calib. coefficient (A1) 4.57

 

Parameter list for programming the photometer Spectroquant® Pharo 100 and Pharo 300

Method number ----
Method-designation Vanadium
Wavelength 405 nm
Citation V
Units mg/l
Resolution 0.01
Zero point (E0) 0.000
Slope (E/C) 0.2188
Meas. range begin 0.50
Meas. range end 5.00
Reference cell 10 mm


Calculation when measuring the absorbance value using the above photometers without programming the method in the memory of the instrument:

Measured absorbance
of samples in A
Result in mg/l
[Asample * 4,57]
1.000 4.57

 

Materials

     
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