Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Dalton transactions (Cambridge, England : 2003) (2007-11-07)

Isabelle Aillaud, Jacqueline Collin, Jérôme Hannedouche, Emmanuelle Schulz

ABSTRACT

The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.

MATERIALS

Product Number

Brand

Product Description

80485

Supelco

Activated charcoal, for the determination of AOX, 50-150 μm particle size

484164

Sigma-Aldrich

Carbon, glassy, spherical powder, 2-12 μm, 99.95% trace metals basis

C9157

Sigma-Aldrich

Activated charcoal, suitable for cell culture, suitable for plant cell culture

31616

Supelco

Activated charcoal, puriss. p.a., powder

05112

Millipore

Activated charcoal, suitable for GC

05105

Supelco

Activated charcoal, powder

29238

Supelco

Activated Charcoal Norit^®, Norit^® RBAA-3, rod

633100

Sigma-Aldrich

Carbon, nanopowder, <100 nm particle size (TEM)

GF65427587

Carbon - Vitreous, rod, 100mm, diameter 3.0mm, glassy carbon

GF13300322

Carbon, foil, 100x100mm, thickness 0.125mm, rigid graphite, fine grain size, 99.95%

GF31110859

Carbon, foil, 100x100mm, thickness 0.25mm, rigid graphite, fine grain size, 99.997%

GF46470944

Carbon, foil, 100x100mm, thickness 0.35mm, flexible graphite, 99.8%

GF44375609

Carbon, foil, 100x100mm, thickness 2.5mm, rigid graphite, fine grain size, 99.95%

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Carbon, foil, 200x200mm, thickness 1.0mm, rigid graphite, fine grain size, 99.95%

GF47838752

Carbon, rod, 50mm, diameter 1.5mm, graphite, 100%

GF46855930

Carbon, microleaf, 50x70mm, thinness 2.5μm, specific density 500μg/cm², 99.997%

GF01171763

Carbon, foil, 50x50mm, thickness 0.35mm, flexible graphite, 99.8%

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Carbon, foil, 25x25mm, thickness 0.5mm, rigid graphite, fine grain size, 99.95%

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Carbon, foil, 10x10mm, thickness 2.0mm, hOpg

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Carbon, rod, 150mm, diameter 6.35mm, graphite, 100%

GF05319468

Carbon, foil, 8mm disks, thickness 0.2mm, flexible graphite, 99.8%

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Carbon, rod, 50mm, diameter 1.0mm, graphite, 99.95%

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Carbon, microleaf, 25x70mm, thinness 0.050μm, specific density 10μg/cm², temporary glass support, 99.997%

GF24548463

Carbon, microleaf, 50x70mm, thinness 1.25μm, specific density 250μg/cm², 99.997%

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Carbon, rod, 50mm, diameter 25mm, graphite, 100%

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