Chemical analogues relevant to molybdenum and tungsten enzyme reaction centres toward structural dynamics and reaction diversity.

Chemical analogues relevant to molybdenum and tungsten enzyme reaction centres toward structural dynamics and reaction diversity.

Chemical Society reviews (2008-11-21)

Hideki Sugimoto, Hiroshi Tsukube

PMID19020675

ABSTRACT

Recent characterisation of molybdenum and tungsten enzymes revealed novel structural types of reaction centres, as well as providing new subjects of interest as synthetic chemical analogues. This tutorial review highlights the structure/reactivity relationships of the enzyme reaction centres and chemical analogues. Chemical analogues for the oxygen atom transfer enzymes have been well expanded in structure and reactivity. Other types of chemical analogues that exhibit different coordination chemistry have recently been presented for reaction centres of the hydroxylation and dehydrogenation enzymes and others.

MATERIALS

Product Number

Brand

Product Description

366986

Sigma-Aldrich

Molybdenum, powder, 10 μm, ≥99.95% trace metals basis

577987

Sigma-Aldrich

Molybdenum, nanopowder, <100 nm particle size (TEM), 99.8% trace metals basis

357200

Sigma-Aldrich

Molybdenum, foil, thickness 1.0 mm, ≥99.9% trace metals basis

266892

Sigma-Aldrich

Molybdenum, powder, <150 μm, 99.9% trace metals basis

357227

Sigma-Aldrich

Molybdenum, foil, thickness 0.025 mm, ≥99.9% trace metals basis

266922

Sigma-Aldrich

Molybdenum, foil, thickness 0.1 mm, ≥99.9% trace metals basis

267546

Sigma-Aldrich

Tungsten, foil, thickness 0.25 mm, ≥99.9% trace metals basis

GF13770491

Tungsten, rod, 50mm, diameter 16mm, centerless ground, 99.95%

GF25095854

Tungsten, rod, 200mm, diameter 5.0mm, centerless ground, 99.95%

GF38214187

Molybdenum, tube, 100mm, outside diameter 1.0mm, inside diameter 0.7mm, wall thickness 0.15mm, 99.9%

GF40454805

Molybdenum, foil, light tested, 25x25mm, thickness 0.005mm, 99.9%

GF04293446

Molybdenum, tube, 500mm, outside diameter 3.15mm, inside diameter 2.39mm, wall thickness 0.38mm, 99.9%

GF18728961

Tungsten, microfoil, disks, 25mm, thinness 0.1μm, specific density 182μg/cm², permanent mylar 3.5μm support, 99.95%

GF31997289

Molybdenum, foil, light tested, 29x500mm, thickness 0.0712mm, annealed, 99.9%

GF24009128

Molybdenum, rod, 100mm, diameter 3.0mm, centerless ground, 99.9%

GF27269635

Molybdenum, rod, 50mm, diameter 25mm, centerless ground, 99.9%

GF61121304

Molybdenum, foil, not light tested, 100x100mm, thickness 0.007mm, 99.9%

GF14696859

Tungsten, rod, 100mm, diameter 10.0mm, centerless ground, 99.95%

GF34073344

Molybdenum, rod, 200mm, diameter 10.0mm, centerless ground, 99.9%

GF22953012

Tungsten, wire reel, 10m, diameter 0.004mm, hard, clean, 99.95%

GF11002149

Molybdenum, foil, not light tested, 100x100mm, thickness 0.01mm, 99.9%

GF15351735

Molybdenum, tube, 50mm, outside diameter 6.4mm, inside diameter 4.6mm, wall thickness 0.9mm, 99.9%

GF18063783

Tungsten, microfoil, disks, 10mm, thinness 0.25μm, specific density 474μg/cm², permanent mylar 3.5μm support, 99.95%

GF25048188

Molybdenum, rod, 100mm, diameter 8.0mm, centerless ground, 99.9%

GF52817878

Tungsten, foil, 30mm disks, thickness 1.0mm, as rolled, 99.95%

GF10563342

Tungsten, foil, not light tested, 50x50mm, thickness 0.007mm, 99.95%

GF12679106

Tungsten, foil, light tested, 25x25mm, thickness 0.015mm, 99.95%

GF37265429

Tungsten, foil, 150x150mm, thickness 0.15mm, as rolled, 99.95%

GF49993048

Molybdenum, microfoil, disks, 25mm, thinness 1.0μm, specific density 1022μg/cm², permanent mylar 3.5μm support, 99.9%

GF59032481

Tungsten, insulated wire, 5m, conductor diameter 0.0125mm, insulation thickness 0.0035mm, polyimide insulation, 99.9%