All Photos(2)

529745

Sigma-Aldrich

Isopropyllithium solution

0.7 M in pentane

Linear Formula:
(CH3)2CHLi
CAS Number:
Molecular Weight:
50.03
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

concentration

0.7 M in pentane

bp

35-36 °C

density

0.632 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li]C(C)C

InChI

1S/C3H7.Li/c1-3-2;/h3H,1-2H3;

InChI key

HDSLTIHESBGENB-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Packaging

4×25, 100 mL in Sure/Seal™
1 L in Sure/Seal™
The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Application

Used in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-31.0 °F - closed cup

Flash Point(C)

-35 °C - closed cup

Certificate of Analysis

Certificate of Origin

David M Hodgson et al.
The Journal of organic chemistry, 71(22), 8510-8515 (2006-10-27)
Organolithium-induced alkylative ring opening of N-sulfonyl-protected aziridinyl ethers is described. The reactions were efficiently carried out with a variety of organolithiums, providing a promising new strategy to unsaturated amino alcohols and ethers. Cis- and trans-1,4-dimethoxybut-2-ene-derived aziridines were prepared, and their

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service