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19997

Sigma-Aldrich

tert-Butyl hydroperoxide solution

packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4Å)

Sinônimo(s):
1,1-Dimethylethyl hydroperoxide, TBHP, 2-Hydroperoxy-2-methylpropane
Fórmula linear:
(CH3)3COOH
Número CAS:
Peso molecular:
90.12
Beilstein:
1098280
Número MDL:
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

100

teor

52.9-66.8% (iodometric)

forma

liquid

qualidade

packed in FEP bottles

reaction suitability

reagent type: oxidant

concentração

~5.5 M in decane (over molecular sieve 4Å)

índice de refração

n20/D 1.403

densidade

0.83 g/mL at 20 °C

temperatura de armazenamento

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Aplicação

Used in oxidative desulfurization of fuelsand as an oxidant for the epoxidation of styrene.

Embalagem

25, 100 mL in PFA/FEP bottle

Outras notas

Safe and stable oxidant for the Sharpless epoxidation

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Ponto de fulgor (ºF)

109.4 °F - closed cup

Ponto de fulgor (ºC)

43 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificado de análise

Certificado de origem

Controlled synthesis of a- and c-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on a-Fe2O3 catalyzed styrene epoxidation.
Bepari RA,et al.
Journal of Saudi Chemical Society (2014)
Oxidative desulfurization of fuel oil. Part I. Oxidation of dibenzothiphenes using tert-butyl hydroperoxide
Wang D,et al.
Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
T. Katsuki et al.
Org. React., 48, 1-1 (1996)
Qiong Tang et al.
Ultrasonics sonochemistry, 20(5), 1168-1175 (2013-03-30)
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The

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