Merck
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206229

Sigma-Aldrich

Ruthenium(III) chloride hydrate

ReagentPlus®

Sinônimo(s):
Ruthenium trichloride
Fórmula linear:
RuCl3 · xH2O
Número CAS:
Peso molecular:
207.43 (anhydrous basis)
Número EC:
Número MDL:
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

200

linha de produto

ReagentPlus®

forma

powder and chunks

composição

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

reaction suitability

reagent type: catalyst
core: ruthenium

Impurezas

≤0.1% Insoluble matter (C=1%, 25% HCl)

SMILES string

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Descrição geral

soluble form

Aplicação

It is used to prepare a nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation arylmethyl alcohols to the corresponding aldehydes. The product catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Ruthenium hydrated oxide, prepared from RhCl3 when deposited on titania nanotubes can be used as a catalyt system for selective oxidation of alcohols by oxygen.

Embalagem

1, 5, 25 g in glass bottle

Informações legais

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Certificado de análise

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Certificado de origem

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Mais documentos

Cotações e pedidos

TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)

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