266086

Sigma-Aldrich

Copper

powder, <425 μm, 99.5% trace metals basis

Empirical Formula (Hill Notation):
Cu
Número CAS:
Peso molecular:
63.55
Número EC:
Número MDL:
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

100

teor

99.5% trace metals basis

forma

powder

reaction suitability

core: copper
reagent type: catalyst

resistividade

1.673 μΩ-cm, 20°C

tamanho de partícula

<425 μm

pb

2567 °C (lit.)

pf

1083.4 °C (lit.)

densidade

8.94 g/mL at 25 °C (lit.)

SMILES string

[Cu]

InChI

1S/Cu

InChI key

RYGMFSIKBFXOCR-UHFFFAOYSA-N

Embalagem

2 kg in glass bottle
25, 500 g in glass bottle

Aplicação

Catalyst for the cyclization and coupling reactions; e.g. Ullmann coupling reactions, preparation of cyclopropanes, decomposition of diazoketones or diazoesters, insertion to C-O bonds, [3 + 2] cycloaddition of terminal alkynes and azides, hydrogenation.

Pictogramas

FlameEnvironment

Palavra indicadora

Danger

Frases de perigo

Equipamento de proteção individual

Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RIDADR

UN3089 - class 4.1 - PG 2 - EHS - Metal powders, flammable, n.o.s., Hi:A,S

WGK Alemanha

WGK 3

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable

Certificado de análise

Certificado de origem

Hiroshi Sato et al.
Science (New York, N.Y.), 343(6167), 167-170 (2013-12-18)
Carbon monoxide (CO) produced in many large-scale industrial oxidation processes is difficult to separate from nitrogen (N2), and afterward, CO is further oxidized to carbon dioxide. Here, we report a soft nanoporous crystalline material that selectively adsorbs CO with adaptable...
Magnus Andersson et al.
Nature structural & molecular biology, 21(1), 43-48 (2013-12-10)
Heavy metals in cells are typically regulated by PIB-type ATPases. The first structure of the class, a Cu(+)-ATPase from Legionella pneumophila (LpCopA), outlined a copper transport pathway across the membrane, which was inferred to be occluded. Here we show by...
Yan Meng et al.
Biochimica et biophysica acta, 1690(3), 208-219 (2004-10-30)
Hepatic abnormalities in Long-Evans Cinnamon (LEC) rats, an animal model of Wilson disease (WD), were restored by the expression of the human ATP7B cDNA under the control of CAG promoter. Expression of ATP7B transcript and protein in the liver of...
Stephen G Kaler et al.
The New England journal of medicine, 358(6), 605-614 (2008-02-08)
Menkes disease is a fatal neurodegenerative disorder of infancy caused by diverse mutations in a copper-transport gene, ATP7A. Early treatment with copper injections may prevent death and illness, but presymptomatic detection is hindered by the inadequate sensitivity and specificity of...
Seonah Kim et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(1), 149-154 (2013-12-18)
Lytic polysaccharide monooxygenases (LPMOs) exhibit a mononuclear copper-containing active site and use dioxygen and a reducing agent to oxidatively cleave glycosidic linkages in polysaccharides. LPMOs represent a unique paradigm in carbohydrate turnover and exhibit synergy with hydrolytic enzymes in biomass...

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