Merck
Todas as fotos(2)

268569

Sigma-Aldrich

Trimethylaluminum solution

2.0 M in hexanes

Fórmula linear:
(CH3)3Al
Número CAS:
Peso molecular:
72.09
Beilstein:
3587197
Número MDL:
ID de substância PubChem:
NACRES:
NA.22

forma

liquid

Nível de qualidade

100

concentração

2.0 M in hexanes

densidade

0.683 g/mL at 25 °C

SMILES string

C[Al](C)C

InChI

1S/3CH3.Al/h3*1H3;

InChI key

JLTRXTDYQLMHGR-UHFFFAOYSA-N

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Categorias relacionadas

Descrição geral

Trimethylaluminum is a Lewis acid having wide applications in organic synthesis. It is employed in organic reactions like cross-coupling reaction, methylenation, carboalumination, cyclopropanation, and rearrangement reactions. Tebbe Reagent (methylenation agent) can be prepared in situ by reacting trimethylaluminum with dichlorobis(cyclopentadienyl)titanium.

Aplicação

Used with 4-bromo-2,6-di-tert-butylphenol (cat. no. 394378) to prepare a wide range of carbonyl compounds via the selective rearrangement of epoxides.

Embalagem

100, 800 mL in Sure/Seal™

Palavra indicadora

Danger

Classificações de perigo

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

Órgãos-alvo

Central nervous system

Perigos de suplementos

Código de classe de armazenamento

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Ponto de fulgor (ºF)

-0.4 °F - closed cup

Ponto de fulgor (ºC)

-18 °C - closed cup

Certificado de análise

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Certificado de origem

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Mais documentos

Quotes and Ordering

Tetrahedron, 47, 6983-6983 (1991)
Tetrahedron Letters, 30, 5607-5607 (1989)
Trimethylaluminum
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2007)
J L L Robinson et al.
Oncogene, 33(50), 5666-5674 (2013-12-03)
Castration-resistant prostate cancer (CRPC) continues to pose a significant clinical challenge with new generation second-line hormonal therapies affording limited improvement in disease outcome. As the androgen receptor (AR) remains a critical driver in CRPC, understanding the determinants of its transcriptional
Shahram Khosravi et al.
The Journal of investigative dermatology, 135(5), 1358-1367 (2015-01-07)
Human cutaneous melanoma is a devastating skin cancer because of its invasive nature and high metastatic potential. We used tissue microarray to study the role of human eukaryotic translation initiation factor 4E (eIF4E) in melanoma progression in 448 melanocytic lesions

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