417939

Sigma-Aldrich

Dimethyl sulfoxide-d6

"100%", 99.96 atom % D, contains 0.03 % (v/v) TMS

Sinônimo(s):
Hexadeuterodimethyl sulfoxide, (Methyl sulfoxide)-d6, DMSO-d6
Fórmula linear:
(CD3)2SO
Número CAS:
Peso molecular:
84.17
Beilstein/REAXYS Number:
1237248
Número EC:
Número MDL:
ID de substância PubChem:
NACRES:
NA.21

Nível de qualidade

100

pressão de vapor

0.42 mmHg ( 20 °C)

pureza isotópica

99.96 atom % D

teor

≥99% (CP)

forma

liquid

temperatura de autoignição

573 °F

contém

0.03 % (v/v) TMS

Lim. expl.

42 %

aplicação(ões)

NMR: suitable

Impurezas

≤0.0250% water
water

índice de refração

n20/D 1.476 (lit.)

pb

189 °C (lit.)

pf

20.2 °C (lit.)

densidade

1.190 g/mL at 25 °C (lit.)

alteração de massa

M+6

SMILES string

[2H]C([2H])([2H])S(=O)C([2H])([2H])[2H]

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3/i1D3,2D3

InChI key

IAZDPXIOMUYVGZ-WFGJKAKNSA-N

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Descrição geral

Dimethyl sulfoxide-d6 (DMSO-d6) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It undergoes photodissociation to generate CD3 radical photoproducts, which have been analyzed by infrared diode laser-absorption spectroscopy. Dissociation dynamics of DMSO-d6 at 193nm was examined using photo fragment translational spectroscopy method.

Aplicação

Dimethyl sulfoxide-d6 (DMSO-d6) may be used as an NMR solvent for 1H and 13C NMR experiments.

Embalagem

10×0.75, 5 mL in ampule
25 mL in glass bottle

storage_class_code

10 - Combustible liquids

WGK Alemanha

WGK 2

Ponto de fulgor (ºF)

190.4 °F

Ponto de fulgor (ºC)

88 °C

Equipamento de proteção individual

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificado de análise

Certificado de origem

Solution forms of an antitumor cyclic hexapeptide, RA-VII in dimethyl sulfoxide-d6 from nuclear magnetic resonance studies.
Itokawa H, et al.
Chemical & Pharmaceutical Bulletin, 40(4), 1050-1052 (1992)
Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of dimethyl sulfoxide-d6.
Rudolph RN, et al.
J. Chem. Phys. , 106(4), 1346-1352 (1997)
Unraveling the dissociation of dimethyl sulfoxide following absorption at 193 nm.
Blank DA, et al.
J. Chem. Phys. , 106(2), 539-550 (1997)
Barbara Parrino et al.
European journal of medicinal chemistry, 94, 367-377 (2015-03-18)
Three new ring systems, pyrido[2',3':3,4]pyrrolo[1,2-a]quinoxalines, pyrido[3',2':3,4]pyrrolo[1,2-a]quinoxalines and pyrido[2',3':5,6]pyrazino[2,1-a]isoindoles, were synthesized through an aza-substitution on the already active isoindolo-quinoxaline system and in particular in the position 7 or 4 of the isoindole moiety and in position 5 of the quinoxaline portion....
Priya P Netalkar et al.
European journal of medicinal chemistry, 79, 47-56 (2014-04-12)
Air and moisture stable coordination compounds of late first row transition metals, viz. Co(II), Ni(II), Cu(II) and Zn(II), with a newly designed ligand, 2-(2-benzo[d]thiazol-2-yl)hydrazono)propan-1-ol (LH), were prepared and successfully characterized using various spectro-analytical techniques. The molecular structures of the ligand...

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