Merck
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62421

Sigma-Aldrich

Lithium aluminum hydride

≥97.0% (gas-volumetric), tablet (~0.5 g each)

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Sinônimo(s):
Lithium tetrahydroaluminate, LAH, Lithium alanate
Fórmula linear:
LiAlH4
Número CAS:
16853-85-3
Peso molecular:
37.95
Número EC:
240-877-9
Número MDL:
MFCD00011075
ID de substância PubChem:
57651883
NACRES:
NA.22

Nível de qualidade

100

teor

≥97.0% (gas-volumetric)

forma

tablet (~0.5 g each)

reaction suitability

reagent type: reductant

pf

125 °C (dec.) (lit.)

SMILES string

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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Categorias relacionadas

Outras notas

Review

Pictogramas

FlameCorrosion
GHS02,GHS05

Palavra indicadora

Danger

Frases de perigo

H260 - H314

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1A - Water-react. 1

Código de classe de armazenamento

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 1

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Certificado de análise

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Certificado de origem

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Mais documentos

Structure Search

Quotes and Ordering

Bulk Quote-Order Product
H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)
I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as
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