86578

Sigma-Aldrich

Tetraethyl orthosilicate

≥99.0% (GC)

Sinônimo(s):
Orthosilicic acid tetraethyl ester, Silicon tetraethoxide, TEOS, Tetraethyl silicate, Tetraethoxysilane, Tetraethoxysilicon(IV)
Fórmula linear:
Si(OC2H5)4
Número CAS:
Peso molecular:
208.33
Beilstein/REAXYS Number:
1422225
Número EC:
Número MDL:
ID de substância PubChem:
NACRES:
NA.22

densidade de vapor

7.2 (vs air)

Nível de qualidade

200

pressão de vapor

<1 mmHg ( 20 °C)

teor

≥99.0% (GC)

forma

liquid

índice de refração

n20/D 1.382 (lit.)
n20/D 1.383

pb

168 °C (lit.)

densidade

0.933 g/mL at 20 °C (lit.)

SMILES string

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

InChI key

BOTDANWDWHJENH-UHFFFAOYSA-N

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Descrição geral

Tetraethyl orthosilicate (TEOS) is an inorganic material that can be used as a silica source for the synthesis of silica-based materials such as silicon dioxide, silicon oxycarbides, silanol, siloxane polymer, and organosilicon thin films for a variety of applications. It can also be used in the synthesis of blended membranes, and the production of aerogel. Other applications include coatings for carpets and other objects.

Aplicação

Tetraethyl orthosilicate (TEOS) can be used:
  • As a reagent along with ferric chloride in the synthesis of dihydropyrimidinones.
  • As a modifier in fabrication of humidity sensing material, poly(2-acrylamido-2-methylpropane sulfonate) (poly-AMPS).
  • As a medium to synthesize triarylamines and diaryl ethers via copper catalyzed, ligand free-Ullmann reaction.
  • As a precursor for the preparation of silica xerogel which finds application in pharmaceutical drug carriers.
  • As a precursor for the synthesis of spherical silica particles by Stober process.

Commonly used as a precursor to prepare xerogel
Will interact with dodecylamine in the formation of intercalation compounds of H+-magadiite and used in a study of mixed-metal bioactive glasses.

Embalagem

1 L in glass bottle
250 mL in glass bottle

Pictogramas

FlameExclamation mark

Palavra indicadora

Warning

hazcat

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Órgãos-alvo

Respiratory system

storage_class_code

3 - Flammable liquids

WGK Alemanha

WGK 1

Ponto de fulgor (ºF)

113.0 °F - closed cup

Ponto de fulgor (ºC)

45 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificado de análise

Certificado de origem

  1. How does the storage temperature relate to shipping conditions?

    The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment. See Shipping and Storage for more information.

  2. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  3. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  4. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  5. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  6. What type of applications can Product No. 86578, Tetraethyl orthosilicate (TEOS), be used in?

    TEOS can be used to synthesize sol-gels or aerogels.

  7. How do you create a sol-gel with Tetraethyl orthosilicate (TEOS), Product No. 86578?

    TEOS can be polymerized with water; the polymerization is based on the hydrolysis or the Si-O-Et groups through forming networks linked by Si-O-Si groups.

  8. How can I accelerate the polymerization of Tetraethyl orthosilicate (TEOS), Product No. 86578?

    The polymerization of TEOS can be accelerated or driven to completion by the addtion of acid or base, both of which serve as a catalyst.

  9. What are the applications of sol-gels formed from Tetraethyl orthosilicate (TEOS), Product No. 86578?

    One of the most improtant application of the sol-gel process is the snythesis of zeolites. Other applications are optical ceramic materials or functionalized biosensors.

  10. What is the vapor pressure of Tetraethyl orthosilicate (TEOS), Product No. 86578, at room temperature?

    The vapor pressure of TEOS at room temperature is 1.5 Torr.

Use of poly (2-acrylamido-2-methylpropane sulfonate) modified with tetraethyl orthosilicate as sensing material for measurement of humidity
Su PG, et al.
Analytica Chimica Acta, 1-2(449), 103-109 (2001)
Ferric chloride/tetraethyl orthosilicate as an efficient system for synthesis of dihydropyrimidinones by Biginelli reaction
Cepanec I, et al.
Tetrahedron, 17(61), 4275-4280 (2005)
The Organosilicon thin Film Deposited Using an Atmospheric Pressure Dual-Frequency 50 kHz/33 MHz Frequency MicroPlasma Jet
Yuan QH, et al.
Contributions to Plasma Physics, 56(9), 870-877 (2016)
Modification of synthetic carpet using chitosan-titania nanocomposite for self-cleaning purposes
Sulaeman MI, et al.
AIP Conference Proceedings, 2175(1), 020077-020077 (2019)
Nanoscale silicon dioxide prepared by sol-gel process
Gao H and Yang J
Modern applied science, 4(9), 152-152 (2010)

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