Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.
John H Enemark et al.
Chemical reviews, 104(2), 1175-1200 (2004-02-12)
Elias Papaconstantinou et al.
Frontiers in bioscience : a journal and virtual library, 8, s813-s825 (2003-09-06)
Polyoxometalates (POM) have a rich and promising photochemical behavior. Upon illumination at the O M CT band (i.e., in UV and near-visible area) become powerful oxidizing reagents able to oxidize various organic compounds. In the process POM undergo stepwise reduction...
Richard R Schrock et al.
Angewandte Chemie (International ed. in English), 42(38), 4592-4633 (2003-10-09)
Catalytic olefin metathesis has quickly emerged as one of the most often-used transformations in modern chemical synthesis. One class of catalysts that has led the way to this significant development are the high-oxidation-state alkylidene complexes of molybdenum. In this review...
Ecotoxicology and environmental safety, 73(6), 1099-1113 (2010-09-16)
Tungsten is a widely used transition metal that has not been thoroughly investigated with regards to its ecotoxicological effects. Tungsten anions polymerize in environmental systems as well as under physiological conditions in living organisms. These polymerization/condensation reactions result in the...
Carlos D Brondino et al.
Current opinion in chemical biology, 10(2), 109-114 (2006-02-17)
Mononuclear molybdenum and tungsten are found in the active site of a diverse group of enzymes that, in general, catalyze oxygen atom transfer reactions. Enzymes of the xanthine oxidase family are the best-characterized mononuclear Mo-containing enzymes. Several 3D structures of...