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Sobre este item
Fórmula empírica (Notação de Hill):
Rh
Número CAS:
Peso molecular:
102.91
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141738
MDL number:
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Estamos aqui para ajudarInChI
1S/Rh
SMILES string
[Rh]
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
assay
99.90%
form
wire
manufacturer/tradename
Goodfellow 274-990-45
resistivity
4.33 μΩ-cm, 20°C
L × diam.
0.1 m × 0.25 mm
bp
3727 °C (lit.)
mp
1966 °C (lit.)
density
12.41 g/cm3 (lit.)
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General description
For updated SDS information please visit www.goodfellow.com.
Legal Information
Product of Goodfellow
Classe de armazenamento
13 - Non Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
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Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
Jeremy M Praetorius et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 4079-4094 (2008-08-09)
The organometallic chemistry of N-heterocyclic carbene complexes of the transition metals has received significant attention over the past ten years, especially with respect to complexes of Pd and Ru. The present Perspective highlights the chemistry of NHC complexes of another
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