Merck
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GF91583264

Rhodium

microfoil, disks, 25mm, thinness 0.25μm, specific density 310μg/cm2, permanent mylar 3.5μm support, 99.99%

Sinônimo(s):
Rhodium, RH004600
Empirical Formula (Hill Notation):
Rh
Número CAS:
Peso molecular:
102.91
Número MDL:
ID de substância PubChem:
NACRES:
NA.23

teor

≥99.99%

manufacturer/tradename

Goodfellow 915-832-64

resistividade

4.33 μΩ-cm, 20°C

pb

3727 °C (lit.)

pf

1966 °C (lit.)

densidade

12.41 g/cm3 (lit.)

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Descrição geral

For updated SDS information please visit www.goodfellow.com.

Informações legais

Product of Goodfellow

Código de classe de armazenamento

13 - Non Combustible Solids

WGK

nwg

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable

Certificado de análise

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Certificado de origem

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Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.
Denise A Colby et al.
Chemical reviews, 110(2), 624-655 (2009-05-15)
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
Albert Padwa
Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)
In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and
Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jerzy Klosin et al.
Accounts of chemical research, 40(12), 1251-1259 (2007-11-14)
A series of bis-phosphite and bis-phosphine ligands for asymmetric hydroformylation reactions has been evaluated. Bis-phosphite ligands lead, in general, to high regioselectivities across a range of substrates while good enantioselectivities are limited to only a few examples. We found that

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