Merck
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15512

Sigma-Aldrich

Formaldehyde solution

meets analytical specification of USP, ≥34.5 wt. %

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Sinônimo(s):
Formalin
Fórmula linear:
HCHO
Número CAS:
50-00-0
Peso molecular:
30.03
Beilstein:
1209228
Número MDL:
MFCD00003274
eCl@ss:
39021101
ID de substância PubChem:
57647382
NACRES:
NA.21

Nível de qualidade

200

densidade de vapor

1.03 (vs air)

pressão de vapor

52 mmHg ( 37 °C)

teor

≥34.5 wt. %

temperatura de autoignição

572 °F

qualidade

meets analytical specification of USP

contém

9.0-15.0% methanol as stabilizer (GC)

concentração

25-50%

Impurezas

acidic reac. substances, complies
 residual solvents, complies

resíduo de ignição

≤0.01% (as SO4)

densidade

1.09 g/mL at 25 °C (lit.)

adequação

corresponds for identity

SMILES string

[H]C([H])=O

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

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Descrição geral

Formaldehyde solution commercially formaldehyde solution is an aqueous solution containing 37% formaldehyde and 8-10% methanol. Formaldehyde solution can be activated by adding the catalytic amount of lanthanide triflate. This activated formaldehyde solution was employed for the smooth hydroxymethylation reaction of silyl enol ethers. Formaldehyde solution reacts with silyl enol ethers to afford the corresponding hydroxymethylated adducts in high yields.

Aplicação

Formaldehyde solution was used to prepare the formaldehyde stock solution for the development of transparent sol-gels with entrapped sensitive and selective reagents for the detection of formaldehyde in air. It may be used in the preparation of nanocrystalline metal (Cu, Hg, Zn, Bi, Pb) sulfides having different shapes and different particle sizes.

Outras notas

The article number 15512-4X2.5L-R will be discontinued. Please order the single bottle 15512-2.5L-R which is physically identical with the same exact specifications.
The article number 15512-6X1L-R will be discontinued. Please order the single bottle 15512-1L-R which is physically identical with the same exact specifications.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 1 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Ponto de fulgor (ºF)

143.6 °F

Ponto de fulgor (ºC)

62 °C

Certificado de análise

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Certificado de origem

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Mais documentos

Structure Search

Quotes and Ordering

Bulk Quote-Order Product
Lanthanide Trifluoromethanesulfonates as Stable Lewis Acids in Aqueous Media. Yb (OTf)3 Catalyzed Hydroxymethylation Reaction of Silyl Enol Ethers with Commercial Formaldehyde Solution.
Kobayashi S.
Chemistry Letters (Jpn), 12, 2187-2190 (1991)
Microwave synthesis of nanocrystalline metal sulfides in formaldehyde solution.
Liao X-H, et al.
Materials Science and Engineering, B, 85(1), 85-89 (2001)
Lanthanide triflates as water-tolerant Lewis acids. Activation of commercial formaldehyde solution and use in the aldol reaction of silyl enol ethers with aldehydes in aqueous media.
Kobayashi S and Hachiya I.
The Journal of Organic Chemistry, 59(13), 3590-3596 (1994)
Opas Bunkoed et al.
Analytica chimica acta, 659(1-2), 251-257 (2010-01-28)
We report the development of transparent sol-gels with entrapped sensitive and selective reagents for the detection of formaldehyde. The sampling method is based on the adsorption of formaldehyde from the air and reaction with beta-diketones (for example acetylacetone) in a
Cindy S Ma et al.
The Journal of experimental medicine, 205(7), 1551-1557 (2008-07-02)
Hyper-immunoglobulin E syndrome (HIES) is a primary immune deficiency characterized by abnormal and devastating susceptibility to a narrow spectrum of infections, most commonly Staphylococcus aureus and Candida albicans. Recent investigations have identified mutations in STAT3 in the majority of HIES
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