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Merck

62118

(R)-(+)-Limonene

analytical standard

Sinônimo(s):

(+)-p-Mentha-1,8-diene, (+)-Carvene, (R)-4-Isopropenyl-1-methyl-1-cyclohexene

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1 ML

R$ 505,00

5 ML

R$ 1.606,00

25 ML

R$ 6.341,00

R$ 505,00


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Sobre este item

Fórmula empírica (Notação de Hill):
C10H16
Número CAS:
Peso molecular:
136.23
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
EC Number:
227-813-5
Beilstein/REAXYS Number:
2204754
MDL number:

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InChI key

XMGQYMWWDOXHJM-JTQLQIEISA-N

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1

SMILES string

CC(=C)[C@@H]1CCC(C)=CC1

grade

analytical standard

vapor density

4.7 (vs air)

vapor pressure

<3 mmHg ( 14.4 °C)

assay

≥99.0% (sum of enantiomers, GC)

optical activity

[α]20/D +115.5±1°, c = 10% in ethanol

shelf life

limited shelf life, expiry date on the label

expl. lim.

6.1 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.473 (lit.), n20/D 1.473

bp

176-177 °C (lit.)

density

0.842 g/mL at 20 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

format

neat

storage temp.

2-8°C

Quality Level

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1 of 4

Este Item
183164CRM4042262122
(R)-(+)-Limonene analytical standard

Supelco

62118

(R)-(+)-Limonene

application(s)

agriculture
cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

application(s)

-

application(s)

cannabis testing
cannabis testing

application(s)

-

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

-

technique(s)

gas chromatography (GC): suitable

technique(s)

-

format

neat

format

-

format

single component solution

format

-

Quality Level

100

Quality Level

200

Quality Level

300

Quality Level

100

grade

analytical standard

grade

-

grade

certified reference material, TraceCERT®

grade

-

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

2-8°C

General description

R)-(+)-Limonene is the R- and the predominant enantiomer of the cyclic monoterpene, limonene. It is present as the major constituent of essential oils extracted from oranges, grapefruits, and lemons. In addition, it is also added as a flavoring agent in different personal and household cleaning products, beverages, and confectionery goods. It is known to possess antioxidant, antimicrobial, antifungal, anti-inflammatory, and anti-carcinogenic properties.[1][1]
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Application

This analytical standard can also be used as follows:
  • Analysis of alcoholic beverages for the determination of (R)-(+)-limonene by differential pulse voltammetry (DPV) using two novel electrochemical sensors
  • Simultaneous determination of limonene and linalool in 10 perfume product samples by two-dimensional high-performance liquid chromatographic (HPLC) method combined with electrospray ionization tandem mass spectrometry (ESI-MS/MS)
  • Determination of the enantiomeric composition of volatile chiral compounds, commonly present in three plant species from the Citrus genus by multidimensional gas chromatography (MDGC) coupled to mass spectrometry (MS)
  • Multi-residue analysis of volatiles and fatty acids found in wild and cultivated fennel samples by a single extraction method and gas chromatographic-flame ionization detection (GC-FID)

Other Notes

Regioselective hydrogenation of the exocyclic double bond[2][3]; Regioselective epoxidation of the endocyclic double bond[4]
This compound is commonly found in plants of the genus: carum mentha salvia

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

Classe de armazenamento

3 - Flammable liquids

wgk

WGK 2

flash_point_f

123.8 °F - closed cup

flash_point_c

51 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number

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Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Whitefly attraction to rosemary (Rosmarinus officinialis L.) is associated with volatile composition and quantity
Sadeh D, et al.
PLoS ONE, 12(5) (2017)
Giuseppe Ferrandino et al.
Clinical and translational gastroenterology, 11(9), e00239-e00239 (2020-10-24)
Liver cirrhosis and its complication - hepatocellular carcinoma (HCC) - have been associated with increased exhaled limonene. It is currently unclear whether this increase is more strongly associated with the presence of HCC or with the severity of liver dysfunction.
R. Baker et al.
Journal of the Chemical Society. Chemical Communications, 414-414 (1987)
Rebecca Jordan et al.
Neuron, 98(6), 1214-1228 (2018-06-05)
The olfactory bulb (OB) is the first site of synaptic odor information processing, yet a wealth of contextual and learned information has been described in its activity. To investigate the mechanistic basis of contextual modulation, we use whole-cell recordings to
T. Kitahara et al.
Tetrahedron, 43, 2689-2689 (1987)

Artigos

A throughput HS-SPME-GC-MS method to analyze volatile compounds in Perilla leaves at low extraction temperatures using four different SPME fibers.

Protocolos

Fast GC analysis of sweet orange essential oil in hexane. Key components identified includes: β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene

Conteúdo relacionado

A cromatografia gasosa separa compostos voláteis na fase gasosa, aplicada em vários setores para controle de qualidade.

Gas chromatography separates volatile compounds in the gas phase, applied in various industries for quality control.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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