Merck
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206911

Sigma-Aldrich

Aluminum chloride

reagent grade, 98%

Linear Formula:
AlCl3
CAS Number:
Molecular Weight:
133.34
Número EC:
Número MDL:
eCl@ss:
38120507
ID de substância PubChem:
NACRES:
NA.21

grau

reagent grade

Nível de qualidade

100

pressão de vapor

1 mmHg ( 100 °C)

teor

98%

forma

powder or chunks

reaction suitability

reagent type: catalyst
core: aluminum

pH

2.4 (20 °C, 100 g/L)

pf

190 °C (lit.)

SMILES string

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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Descrição geral

Aluminum chloride participates in the amination of exo-2-chloronorbornane to afford 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane. It has been reported to promote the Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene.

Aplicação

Aluminum chloride has been employed for the estimation of total contents of flavonoids in a freeze-dried extract isolated from Issopus officinalis. It has been employed for the synthesis of the following compounds:
  • 3′-methyl-5′,6′,7′,7a′-tetrahydro-4′H-spiro(cyclohexane-1,1′-isobenzofuran)
  • trans-methyl 2-(cyclohex-1-enyl)cyclohexyl ketone
  • 1,1,3-trimethyl-1,4,5,6,7,7a-hexahydroisobenzofuran
  • 1-((2R*,4aS*,8aR*)-2-methyldecahydronaphthalen-4ayl)ethanone
Aluminum chloride may be used as catalyst for the Friedel-Crafts polymerizations of 4-(trifluoromethoxy)benzyl bromide. It may be employed as catalyst for Fries rearrangement of phenyl isobutyrate at 140°C to afford a mixture of 2-hydroxy- and 4-hydroxy-isobutyrophenone.
It may be used to catalyze:
  • Degradation of polystyrene to benzene.
  • Carbonization of polycyclic aromatic hydrocarbons.
  • Colorimetric microassay of hydroperoxides.

Embalagem

100 g in glass bottle
1 kg in glass bottle

Características e benefícios

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

Pictogramas

Corrosion

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1B

Perigos de suplementos

Código de classe de armazenamento

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 1

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable

Certificate of Analysis

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Certificate of Origin

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