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34998

Sigma-Aldrich

Acetonitrilo

Acetonitrile
1 of 1 reviewers received a sample product or took part in a promotion

≥99.9%, HPLC Plus, suitable for IR spectroscopy, HPLC

Sinônimo(s):

ACN, Cianeto de metila, Cianometano, Etil-nitrilo

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About This Item

Fórmula linear:
CH3CN
Número CAS:
Peso molecular:
41.05
Beilstein:
741857
Número CE:
Número MDL:
Código UNSPSC:
41116105
eCl@ss:
39031501
ID de substância PubChem:
NACRES:
NA.03
Preço e disponibilidade não estão disponíveis no momento.

Nome do produto

Acetonitrilo, HPLC Plus, ≥99.9%

grau

HPLC Plus

Nível de qualidade

densidade de vapor

1.41 (vs air)

pressão de vapor

72.8 mmHg ( 20 °C)

Ensaio

≥99.9%

Formulário

liquid

temperatura de autoignição

973 °F

Lim. expl.

16 %

baseline drift measuring range

≤12 mAU (210 nm)

técnica(s)

HPLC: suitable
IR spectroscopy: suitable

Impurezas

≤0.0001% free alkali (as NH3)
≤0.0002% non-volatile matter
≤0.001% free acid (as CH3COOH)
≤0.01% water (Karl Fischer)
≤0.5 ppb fluorescence (quinine) at 254 nm
≤0.5 ppb fluorescence (quinine) at 365 nm

resíduo halogenado

10 ng/L (as heptachlor epoxide)

índice de refração

n20/D 1.344 (lit.)

p.e.

81-82 °C (lit.)

pf

−45 °C (lit.)

densidade

0.786 g/mL at 25 °C (lit.)

Gradiente HPLC

≤0.2 mAU at 254 nm
≤1 mAU at 210 nm

λ

H2O reference

Absorção UV

λ: 195 nm Amax: ≤0.10
λ: 200 nm Amax: ≤0.02
λ: 228 nm Amax: ≤0.005
λ: 235 nm Amax: ≤0.0044
λ: 250 nm Amax: ≤0.0044
λ: 400 nm Amax: ≤0.0044

aplicação(ões)

food and beverages

Formato

neat

cadeia de caracteres SMILES

CC#N

InChI

1S/C2H3N/c1-2-3/h1H3

chave InChI

WEVYAHXRMPXWCK-UHFFFAOYSA-N

Procurando produtos similares? Visita Guia de comparação de produtos

Descrição geral

O acetonitrilo (MeCN) é amplamente usado como solvente em vários estudos e tem uma constante dielétrica alta (37,5). Vários procedimentos de purificação para obter graus diferentes de acetonitrilo para uso em diferentes estudos (polarografia, espectroscopia, etc.) foram relatados por diversos pesquisadores.[1]

Aplicação

O acetonitrilo foi usado para compor o sistema de gradiente para detecção por HPLC de di-isocianato de difenilmetano, um produto de degradação polimérico.[2]
O novo acetonitrilo de qualidade para UPLC Plus é adequado para todas as aplicações, inclusive:
espectrometria de massa, HPLC, TLC, GPC, UV, IR, GC, análise de resíduos de pesticidas e síntese e purificação de RNA/DNA.

Embalagem

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

Nota de preparo

Produto filtrado em filtro de 0,2 μm

Outras notas

Recipientes Pure-Pac® II requerem o acoplador Micromatic MacroValve para dispensação de solventes, Z560723.
Aviso importante
  • O artigo número 34998-4X2.5L será descontinuado. Encomende o frasco único 34998-2.5L, que é fisicamente idêntico, com exatamente as mesmas especificações.
  • O artigo número 34998-6X1L será descontinuado. Encomende o frasco único 34998-1L, que é fisicamente idêntico, com exatamente as mesmas especificações.

Produtos recomendados

Descubra os reagentes LiChropur ideais para análise por HPLC ou LC-MS

Informações legais

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

FlameExclamation mark

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

35.6 °F - closed cup

Ponto de fulgor (°C)

2.0 °C - closed cup


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Certificados de análise (COA)

Lot/Batch Number

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Acetonitrilo

H Haugen et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 73(2), 229-237 (2005-03-10)
This article deals with enzyme-induced biodegradation behavior of thermoplastic polyether-urethane (TPU). Porous scaffolds were processed by a new foaming method applied in hot pressing and injection molding. The scaffolds were subsequently gamma sterilized. The samples were incubated with cholesterol esterase
Alexander David Ardianrama et al.
Journal of colloid and interface science, 552, 485-493 (2019-06-04)
Although triangular silver (Ag) nanoplates are intrinsically unstable, this characteristic has been taken advantage of in the development of a novel sensing platform. However, most of these applications have relied on halide ions as etchants. In the current work, we
Purification of acetonitrile.
Walter M and Ramaley L.
Analytical Chemistry, 45(1), 165-166 (1973)
Timo Glatter et al.
Molecular systems biology, 5, 237-237 (2009-01-22)
Protein complexes represent major functional units for the execution of biological processes. Systematic affinity purification coupled with mass spectrometry (AP-MS) yielded a wealth of information on the compendium of protein complexes expressed in Saccharomyces cerevisiae. However, global AP-MS analysis of
Elke H J Krekels et al.
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From a previously validated paediatric population pharmacokinetic model, it was derived that non-linear morphine maintenance doses of 5 μg/kg(1.5)/h, with a 50 % dose reduction in neonates with a postnatal age (PNA) <10 days, yield similar morphine and metabolite concentrations

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Conteúdo relacionado

The 4L M-Bottle provides safe handling of solvents due to an innovative solvent bottle design with sealing technology to eliminate leaks and reduce risks in solvent dispensing.

Questions

1–9 of 9 Questions  
  1. What kind of container is used for the 4L? Is a photo available?

    1 answer
    1. This product is packaged in a 4L amber glass bottle with a teflon-lined polypropylene screw cap. Unfortunately, an image is not available.

      Helpful?

  2. What kind of container is used for the 20L? Is a photo available?

    1 answer
    1. This product is packaged in a 20 liter HDPE drum. Please see the picture attached below.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  5. What are the options for drying solvents?

    1 answer
    1. Sigma-Aldrich offers a full range of high-purity solvents with extremely low water levels specifically manufactured for moisture sensitive Organic and Biotech applications.  Sigma-Aldrich also carries various drying agents such as molecular sieves, which are typically compatible with organic solvents.

      Helpful?

  6. Can you recommend a Solvent Extractor for organics from aqueous solution?

    1 answer
    1. Solvent extractors are often used for the quantitative extraction of organics from aqueous solutions and separations in immunoassays. The MIXXOR system has been applied successfully in many laboratory solvent extraction operations and is ideal for the rapid screening of alternative solvents for specific extraction problems.

      Helpful?

  7. What apparatus do you recommend for HPLC solvent filtration?

    1 answer
    1. The Sigma-Aldrich Vacuum Filtration Assembly gives you all the components you need including: funnel top, fritted glass funnel support, filtration flask, aluminum clamp, and silicone stopper.  The Acrodisc Syringe Filters offer high quality filtration for analytical samples, certified for HPLC to ensure low extractable and available in a broad range of membranes to meet sample compatibility requirements.

      Helpful?

  8. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  9. Who do I contact about larger solvent volume needs?

    1 answer
    1. Email us at [email protected] or visit Sigma-Aldrich Fine Chemicals for development and manufacturing-scale inquiries: [email protected]

      Helpful?

Reviews

1 of 1 reviewers received a sample product or took part in a promotion

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