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425044

Sigma-Aldrich

Hipoclorito de sódio

greener alternative

reagent grade, available chlorine 10-15 %

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About This Item

Fórmula linear:
NaClO
Número CAS:
Peso molecular:
74.44
Número MDL:
Código UNSPSC:
12161902
ID de substância PubChem:
NACRES:
NA.21
Preço e disponibilidade não estão disponíveis no momento.

grau

reagent grade

Nível de qualidade

Agency

suitable for SM 4500 - NH3

pressão de vapor

23.3 hPa ( 20 °C)

Formulário

liquid

composição

available chlorine, 10-15%

adequação da reação

reagent type: oxidant

características do produto alternativo mais ecológico

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentração

10-15% (chlorine by Na2S2O3, titration)

p.e.

111 °C

densidade

1.206 g/mL at 25 °C

categoria alternativa mais ecológica

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

[Na+].[O-]Cl

InChI

1S/ClO.Na/c1-2;/q-1;+1

chave InChI

SUKJFIGYRHOWBL-UHFFFAOYSA-N

Procurando produtos similares? Visita Guia de comparação de produtos

Descrição geral

A eficácia da solução de hipoclorito de sódio (NaOCl) 2,5% como irrigante endodôntico foi testada.[1] Seu uso como solvente de tecidos foi proposto. O efeito do tempo e das condições de armazenamento na capacidade de diversas concentrações de NaOCl de dissolver tecidos foi estudado.[2] [3]
Estamos comprometidos em trazer para você produtos alternativos mais ecológicos, que aderem a um ou mais dos 12 princípios de química ecológica (The 12 Principles of Green Chemistry). Este produto é considerado um oxidante não nocivo ao meio ambiente e foi elevado à categoria de "solventes e auxiliares mais seguros". Clique aqui para obter mais informações.

Aplicação

O hipoclorito de sódio é um oxidante usado com o composto TEMPO catalítico para oxidação de alcoóis. Ele é usado geralmente na síntese de 3,3′-bis(sulfonato)-4,4′-bis(acetamido)azobenzeno sódico.[4]

(Artigo em inglês) Towards greener solvents for the bleach oxidation of alcohols catalysed by stable N-oxy radicals

Exoneração de responsabilidade

O produto não se destina ao uso como biocida sob as normas biocidas globais, incluindo, entre outros, Lei Federal de Inseticidas, Fungicidas e Rodenticidas da EPA dos EUA, Regulamento Europeu de Produtos Biocidas, Agência Reguladora de Gestão de Pragas do Canadá, Regulamento de Produtos Biocidas da Turquia, Lei de Gestão de Segurança de Produtos Químicos e Biocidas do Consumidor da Coreia (K-BPR) e outros.

Pictogramas

CorrosionEnvironment

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Perigos de suplementos

Código de classe de armazenamento

8B - Non-combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Melanie Hillion et al.
Scientific reports, 7(1), 1195-1195 (2017-04-28)
Mycothiol (MSH) is the major low molecular weight (LMW) thiol in Actinomycetes. Here, we used shotgun proteomics, OxICAT and RNA-seq transcriptomics to analyse protein S-mycothiolation, reversible thiol-oxidations and their impact on gene expression in Mycobacterium smegmatis under hypochlorite stress. In
Ruoyu Guo et al.
International journal of genomics, 2015, 484626-484626 (2015-06-13)
The marine dinoflagellate Cochlodinium polykrikoides is responsible for harmful algal blooms in aquatic environments and has spread into the world's oceans. As a microeukaryote, it seems to have distinct genomic characteristics, like gene structure and regulation. In the present study
Effects of the algicides CuSO4 and NaOCl on various physiological parameters in the harmful dinoflagellate Cochlodinium polykrikoides.
Ebenezer V, et al.
Journal of Applied Phycology, 26(6), 2357-2365 (2014)
Ian Morrissey et al.
PloS one, 9(1), e86669-e86669 (2014-01-28)
To date there are no clear criteria to determine whether a microbe is susceptible to biocides or not. As a starting point for distinguishing between wild-type and resistant organisms, we set out to determine the minimal inhibitory concentration (MIC) and
Eun Jo Du et al.
PLoS genetics, 12(1), e1005773-e1005773 (2016-01-05)
Pathogen expulsion from the gut is an important defense strategy against infection, but little is known about how interaction between the intestinal microbiome and host immunity modulates defecation. In Drosophila melanogaster, dual oxidase (Duox) kills pathogenic microbes by generating the

Artigos

Overview on how to maintain proper cell culture laboratory safety including steps on performing lab risk assessments, surface disinfection, biohazard and waste removal. Free ECACC handbook download.

Protocolos

Cell culture protocol for proper aseptic technique to maintain a sterile environment and to prevent cell culture contamination. Free ECACC handbook download.

Conteúdo relacionado

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Questions

1–8 of 8 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. How was the titration done for 425044, and how was the percent for the COA obtained?

    1 answer
    1. The quality level of the product is 100, no information can be provided on the tests that are run on the COA.

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  4. Please provide information on whether the 10-15% concentration of this solution is by weight/weight, volume/volume, or something else.

    1 answer
    1. The chlorine concentration is reported as Weight/Weight (W/W) for this product.

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  5. Is this material %(W/V) or %(W/W) for the available chlorine titration.

    1 answer
    1. It is % (W/W).

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  6. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  7. How is available chlorine tested?

    1 answer
    1. To analyze for available chlorine, a sample of sodium hypochlorite is added to a solution of potassium iodide in the presence of acid to liberate iodine.  The liberated iodine is titrated with standardized sodium thiosulfate.

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  8. What is the definition of available chlorine?

    1 answer
    1. Available chlorine is a measure of the bleaching power of a substance. Available chlorine is defined as chlorine capable of releasing an equivalent amount of atomic oxygen according to the following reaction equations.Cl2 + 2OH- --> OCl- + Cl- + H2O  (eqn. 1) HOCl --> HCl + ½ O2  (eqn. 2)

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