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G4022

Sigma-Aldrich

Cloreto de ouro(III)

ACS reagent, ≥49.0% Au basis

Sinônimo(s):
Tetracloroaurato(III) de hidrogênio, Ácido tetracloroáurico(III)
Fórmula linear:
HAuCl4 · 3H2O
Número CAS:
Peso molecular:
393.83
Número EC:
Número MDL:
ID de substância PubChem:
NACRES:
NA.21

grau

ACS reagent

forma

powder, crystals or chunks

reaction suitability

reagent type: catalyst
core: gold

concentração

≥49.0% Au

Impurezas

≤0.1% Insoluble in ether

traços de cátion

alkalies and other metals (as sulfates): ≤0.2%

temperatura de armazenamento

2-8°C

SMILES string

Cl[H].[H]O[H].[H]O[H].[H]O[H].Cl[Au](Cl)Cl

InChI

1S/Au.4ClH.3H2O/h;4*1H;3*1H2/q+3;;;;;;;/p-3

InChI key

XYYVDQWGDNRQDA-UHFFFAOYSA-K

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Este Item
254169379948520918
Gold(III) chloride trihydrate ACS reagent, ≥49.0% Au basis

Sigma-Aldrich

G4022

Gold(III) chloride trihydrate

Gold(III) chloride hydrate 99.995% trace metals basis

Sigma-Aldrich

254169

Gold(III) chloride hydrate

Gold(III) chloride ≥99.99% trace metals basis

Sigma-Aldrich

379948

Gold(III) chloride

Gold(III) chloride trihydrate ≥99.9% trace metals basis

Sigma-Aldrich

520918

Gold(III) chloride trihydrate

form

powder, crystals or chunks

form

crystals and lumps

form

solid

form

crystals and lumps

impurities

≤0.1% Insoluble in ether

impurities

≤55.0 ppm Trace Metal Analysis

impurities

≤100.0 ppm Trace Metal Analysis

impurities

≤1000.0 ppm Trace Metal Analysis

cation traces

alkalies and other metals (as sulfates): ≤0.2%

cation traces

-

cation traces

-

cation traces

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

reaction suitability

reagent type: catalyst
core: gold

reaction suitability

reagent type: catalyst
core: gold

reaction suitability

reagent type: catalyst
core: gold

reaction suitability

-

Aplicação

Gold(III) chloride trihydrate can be used as a gold precursor salt for the production of gold nanoparticles (AuNP) using various reducing agents.
It can also be used as a catalyst in the following processes:
  • HAuCl4 3H2O inPEG 400 is used to synthesize spirochromene derivatives via a one-pot three-component reaction of isatins/acenaphthoquinone, active methylene compounds, and cyclic 1,3-diketones/4-hydroxycoumarin.      
  • Au/CeO2 catalytic system is used in chemoselective oxidation of aromatic/aliphatic alcohols to corresponding carbonyl compounds.      
  • Used in the synthesis of allylnaphthalenes by ring-opening of 1,4-epoxy-1,4-dihydronaphthalenes with allyltrimethylsilane.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

Órgãos-alvo

Kidney

Código de classe de armazenamento

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 3

Ponto de fulgor (ºF)

Not applicable

Ponto de fulgor (ºC)

Not applicable


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Potassium gold(III) chloride 99.995% trace metals basis

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Potassium gold(III) chloride

Efficient chemoselective alcohol oxidation using oxygen as oxidant. Superior performance of gold over palladium catalysts
Abad A, et al.
Tetrahedron, 62(28), 6666-6672 (2006)
Regioselective Gold-Catalyzed Allylative Ring Opening of 1, 4-Epoxy-1, 4-dihydronaphthalenes
Sawama Y, et al.
Synlett, 2010(14), 2151-2155 (2010)
Gold (III) chloride (HAuCl4.3H2O) in PEG: A new and efficient catalytic system for the synthesis of functionalized spirochromenes
Kidwai M, et al.
Applied Catalysis A: General, 425, 35-43 (2012)
Sang Hui Jun et al.
Journal of nanoscience and nanotechnology, 14(8), 6202-6208 (2015-05-06)
Traditional medicinal plants possess diverse active constituents for exerting their biological activities. Recently, the innovative applications of plant extracts have revealed their promise as 'green' reducing agents for the reduction of metal ions during the synthesis of metallic nanoparticles. Herein
Synthesis and stability of fluorescent gold nanoparticles by sodium borohydride in the presence of mono-6-deoxy-6-pyridinium-?-cyclodextrin chloride
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The Journal of Physical Chemistry C, 112(2), 443-451 (2008)

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