• Início
  • Resultados da busca
  • Direct physical exfoliation of few-layer graphene from graphite grown on a nickel foil using polydimethylsiloxane with tunable elasticity and adhesion.

Direct physical exfoliation of few-layer graphene from graphite grown on a nickel foil using polydimethylsiloxane with tunable elasticity and adhesion.

Nanotechnology (2013-04-20)
Kwanghyun Yoo, Yusuke Takei, Sungjin Kim, Shohei Chiashi, Shigeo Maruyama, Kiyoshi Matsumoto, Isao Shimoyama
RESUMO

We firstly introduce a facile method for the site-specific direct physical exfoliation of few-layer graphene sheets from cheap and easily enlargeable graphite grown on a Ni foil using an optimized polydimethylsiloxane (PDMS) stamp. By decreasing the PDMS cross-linking time, the PDMS elasticity is reduced to ∼52 kPa, similar to that of a typical gel. As a result of this process, the PDMS becomes more flexible yet remains in a handleable state as a stamp. Furthermore, the PDMS adhesion to a graphite/Ni surface, as measured by the peel strength, increases to ∼5.1 N m⁻¹, which is approximately 17 times greater than that of typical PDMS. These optimized properties allow the PDMS stamp to have improved contact with the graphite/Ni surface, including the graphite wrinkles. This process is verified, and changes in surface morphology are observed using a 3D laser scanning microscope. Under conformal contact, the optimized PDMS stamp demonstrates the site-specific direct physical exfoliation of few-layer graphene sheets including mono- and bi-layer graphene sheets from the graphite/Ni substrate without the use of special equipment, conditions or chemicals. The number of layers of the exfoliated graphene and its high quality are revealed by the measured Raman spectroscopy. The exfoliation method using tunable elasticity and adhesion of the PDMS stamp can be used not only for cost-effective mass production of defect-less few-layer graphene from the graphite substrate for micro/nano device arrays but also for nano-contact printing of various structures, devices and cells.

MATERIAIS
Número do produto
Marca
Descrição do produto

Nickel, foil, 50x50mm, thickness 0.30mm, as rolled, 99.98%
Nickel, foil, light tested, 100x100mm, thickness 0.015mm, 99.9%
Nickel, foil, 10mm disks, thickness 0.15mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.075mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.075mm, as rolled, 99.98%
Nickel, foil, 4mm disks, thickness 0.125mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.125mm, annealed, 99.98%
Nickel, foil, 4mm disks, thickness 0.125mm, as rolled, 100%
Nickel, foil, 4mm disks, thickness 0.125mm, as rolled, 99.99+%
Nickel, foil, 4mm disks, thickness 0.15mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.1mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.20mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.25mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.25mm, annealed, 99.98%
Nickel, foil, 4mm disks, thickness 0.25mm, as rolled, 100%
Nickel, foil, 4mm disks, thickness 0.25mm, as rolled, 99.99+%
Nickel, foil, 4mm disks, thickness 0.30mm, as rolled, 99.98%
Nickel, foil, 4mm disks, thickness 0.3mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.3mm, as rolled, 100%
Nickel, foil, 4mm disks, thickness 0.50mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.5mm, annealed, 99.98%
Nickel, foil, 4mm disks, thickness 0.5mm, as rolled, 100%
Nickel, foil, 4mm disks, thickness 0.5mm, as rolled, 99.99+%
Nickel, foil, 50mm disks, thickness 0.0025mm, 99.95%
Nickel, foil, 50mm disks, thickness 0.003mm, 99.95%
Nickel, foil, 50mm disks, thickness 0.005mm, as rolled, 99.9%
Nickel, foil, 50mm disks, thickness 0.0075mm, 99.9%
Nickel, foil, 50mm disks, thickness 0.0075mm, 99.95%
Nickel, foil, 50mm disks, thickness 0.0125mm, 99.9%
Nickel, foil, 50mm disks, thickness 0.0125mm, 99.99+%

Redes sociais

LinkedIn icon
Twitter icon
Facebook Icon
Instagram Icon

Merck

Pesquisa. Desenvolvimento. Produção.

Somos um fornecedor global líder para o setor de ciências biológicas, com soluções e serviços para pesquisa, desenvolvimento e produção de biotecnologia, além de produção e desenvolvimento de terapias farmacológicas com medicamentos.

© 2021 Merck KGaA, Darmstadt, Alemanha e/ou suas filiais. Todos os direitos reservados.

A reprodução não autorizada de quaisquer materiais deste site é estritamente proibida.