Palladium and organocatalysis: an excellent recipe for asymmetric synthesis.

Molecules (Basel, Switzerland) (2013-08-27)
M Angeles Fernández-Ibañez, Beatriz Maciá, Diego A Alonso, Isidro M Pastor
RESUMO

The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric a-allylation of carbonyl compounds, a-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology.

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