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233706

Sigma-Aldrich

Vanadium(IV) oxide sulfate hydrate

97%

Synonym(s):

Vanadyl sulfate hydrate

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About This Item

Linear Formula:
VOSO4 · xH2O
CAS Number:
Molecular Weight:
163.00 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97%

form

powder

composition

Degree of hydration, 3-5

reaction suitability

reagent type: catalyst
core: vanadium

mp

105 °C (lit.)

application(s)

battery manufacturing

SMILES string

O=[V++].[H]O[H].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.H2O.O.V/c1-5(2,3)4;;;/h(H2,1,2,3,4);1H2;;/q;;;+2/p-2

InChI key

DKCWBFMZNUOFEM-UHFFFAOYSA-L

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General description

Vanadium (IV) oxide sulfate hydrate is a blue crystalline solid. It is soluble in water and posseses weak oxidizing or reducing properties.

Application

Vanadium (IV) oxide sulfate hydrate has been used to generate vanadiumions, which can be introduced in saponite clay by hydrothermal process.

VOSO4 and anthraquinone-2,7-disulfonicacid can be used as a redox couple to prepare aqueous organic redox flowbattery (AORFB) stack.

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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On the properties of a novel V-containing saponite catalyst for propene oxidative dehydrogenation
Carniato F, et al.
Catalysis Letters, 132(1-2), 42-48 (2009)
Alessandro Chieregato et al.
ChemSusChem, 8(2), 398-406 (2014-12-10)
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