919772
Tris(dibenzylideneacetone)dipalladium(0) ChemBeads
solid
Synonym(s):
Pd2dba3, Pd2(dba)3
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About This Item
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Product Name
Tris(dibenzylideneacetone)dipalladium(0) ChemBeads,
form
solid
Quality Level
composition
~ 5 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
storage temp.
2-8°C
SMILES string
O=C(/C=C/c1ccccc1)/C=C/c2ccccc2.O=C(/C=C/c3ccccc3)/C=C/c4ccccc4.O=C(/C=C/c5ccccc5)/C=C/c6ccccc6.[Pd].[Pd]
InChI
1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;
InChI key
CYPYTURSJDMMMP-WVCUSYJESA-N
1 of 4
This Item | 683345 | 328774 | 366315 |
|---|---|---|---|
| reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability - |
| form solid | form powder | form powder | form solid |
| Quality Level 100 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| composition ~ 5 wt.% loading of catalyst | composition - | composition - | composition - |
Application
Reactant involved in:
- Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
- Preparation of palladium triphenylphosphine carbonyl cluster complexes
- Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
- Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes
Catalyst for:
- Suzuki cross-coupling reactions
- PCN- and PCS-pincer palladium complex catalyzed tandem allylation
Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (328774)
Other Notes
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Legal Information
Additional information available at www.pmc.umicore.com
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Carc. 1B Inhalation - Skin Sens. 1
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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