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221473

Potassium hydroxide

ACS reagent, ≥85%, pellets

Potassium hydroxide

Synonym(s):

Caustic potash

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Size/SKUAvailabilityPrice
25 g
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$41.50
500 g
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$79.90
1 kg
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$149.00
2.5 kg
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$260.00
6 x 500 g
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$425.00
4 x 2.5 kg
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$583.00
12 kg
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$675.00

About This Item

Linear Formula:
KOH
CAS Number:
Molecular Weight:
56.11
PubChem Substance ID:
eCl@ss:
38100303
UNSPSC Code:
12352106
NACRES:
NA.21
EC Number:
215-181-3
MDL number:
Assay:
≥85%
Grade:
ACS reagent
Form:
pellets
Solubility:
water: soluble

$41.50


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grade

ACS reagent

Quality Segment

agency

suitable for EPA 1621, suitable for EPA 1633

vapor pressure

1 mmHg ( 719 °C)

assay

≥85%

form

pellets

impurities

≤0.001% N compounds, ≤2.0% K2CO3, 10-15% water

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

solubility

water: soluble

anion traces

chloride (Cl-): ≤0.01%, phosphate (PO43-): ≤5 ppm, sulfate (SO42-): ≤0.003%

cation traces

Ca: ≤0.005%, Fe: ≤0.001%, Mg: ≤0.002%, Na: ≤0.05%, Ni: ≤0.001%, heavy metals: ≤0.001% (by ICP)

application(s)

PFAS testing

storage temp.

room temp

SMILES string

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

General description

Potassium hydroxide is an inorganic salt mainly used as a precursor to synthesize other potassium compounds such as potassium acetate, potassium bicarbonate and potassium carbonate. On a commercial scale, it is synthesized by the electrolysis of potassium chloride.

Application

Potassium hydroxide may be used in the following processes:
  • Conversion of nitriles to amide in tert-butanol.
  • Cross-coupling of aryl halides with different sulfur-, oxygen- and nitrogen-based nucleophiles in dimethyl sulfoxide.
  • As an activator for the preparation of activated carbons from corn cobs.
  • As a base for the N-alkylation of nitrogen heterocycles in polyethylene glycol-ether solvents.
  • Synthesis of (S)-1-(4-benzyl-2-thioxothiazolidin-3-yl)propan-1-one from (S)-phenylalaninol.
  • To catalyze the polymerization of propylene oxide.

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1 of 1

This Item
P1767306568P5958
form

pellets

form

pellets

form

pellets

form

pellets

assay

≥85%

assay

≥85% KOH basis

assay

99.99% trace metals basis (Purity excludes sodium content.)

assay

≥85% KOH basis

solubility

water: soluble

solubility

water: soluble ((1,130 g/l (68 °F / 20 °C))

solubility

water: soluble

solubility

H2O: 1 M, clear, colorless

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

grade

ACS reagent

grade

-

grade

semiconductor grade

grade

-

anion traces

chloride (Cl-): ≤0.01%, sulfate (SO42-): ≤0.003%, phosphate (PO43-): ≤5 ppm

anion traces

-

anion traces

-

anion traces

chloride (Cl-): ≤0.01%, sulfate (SO42-): ≤0.003%


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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