32293

Hexane

≥99% (GC), ACS reagent, puriss. p.a., reag. Ph. Eur.

• Synonym(s): n-Hexane
• Linear Formula: CH₃(CH₂)₄CH₃
• CAS Number: 110-54-3
• Molecular Weight: 86.18
• NACRES: NA.21
• PubChem Substance ID: 329754126
• UNSPSC Code: 12352001
• EC Number: 203-777-6
• MDL number: MFCD00009520
• Beilstein/REAXYS Number: 1730733
• Assay: ≥99% (GC)
• Technique(s): GC/MS: suitable
• Bp: 69 °C (lit.)
• Vapor pressure: 256 mmHg ( 37.7 °C), 5.2 psi ( 37.7 °C), ~132 mmHg ( 20 °C)

Properties

• Product Name: Hexane, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99% (GC)
• Quality Segment: 200
• agency: reag. Ph. Eur.
• vapor density: ~3 (vs air)
• vapor pressure: 256 mmHg ( 37.7 °C), 5.2 psi ( 37.7 °C), ~132 mmHg ( 20 °C)
• grade: ACS reagent, puriss. p.a.
• assay: ≥99% (GC)
• form: liquid
• autoignition temp.: 453 °F
• expl. lim.: 7.7 %
• technique(s): GC/MS: suitable
• impurities: ≤0.0001% thiophene, ≤0.001% non-volatile matter, ≤0.002% free acid (as CH₃COOH), ≤0.005% S-compounds (as S), ≤0.01% aromatic substances (as C₆H₆), ≤0.01% water (Karl Fischer)
• refractive index: n20/D 1.3745-1.3755, n20/D 1.375 (lit.)
• pH: 7
• bp: 69 °C (lit.)
• mp: −95 °C (lit.)
• density: 0.659 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sn: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
• SMILES string: CCCCCC
• suitability: passes test for reaction against H₂SO₄
• InChI: 1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3
• InChI key: VLKZOEOYAKHREP-UHFFFAOYSA-N

Description

General description

Hexane is an alkane hydrocarbon having 5 structural isomeric forms. It is a colorless, combustible liquid. It is one of the essential components of petroleum ether. It can be obtained from petroleum by distillation. It can also be produced by electrolysis of potassium butyrate. It is widely employed organic solvent for the dissolution of fats and oils.

Application

Hexane has been used in the preparation of graft-copolymer chains of poly-(dimethylsiloxane)-g-poly(methyl methacrylate).[1] It has been employed for the GC/MS characterization of essential oils extracted from various origins.

Analysis Note

boiling range 67-69°C min. 95%; density (D 20/20) 0.659-0.663

Other Notes

Pertains only in Germany: unversteuert

The article number 32293-4X2.5L will be discontinued. Please order the single bottle 32293-2.5L which is physically identical with the same exact specifications.
The article number 32293-4X2.5L-M will be discontinued. Please order the single bottle 32293-2.5L-M which is physically identical with the same exact specifications.
The article number 32293-6X1L will be discontinued. Please order the single bottle 32293-1L which is physically identical with the same exact specifications.
The article number 32293-6X1L-M will be discontinued. Please order the single bottle 32293-1L-M which is physically identical with the same exact specifications.

Safety Information

• pictograms: GHS02,GHS08,GHS07,GHS09
• signalword: Danger
• pcodes: P202 - P210 - P273 - P301 + P310 - P303 + P361 + P353 - P331
• target_organs: Central nervous system, Nervous system
• Storage Class: 3 - Flammable liquids
• flash_point_f: -7.6 °F - closed cup
• flash_point_c: -22 °C - closed cup
• hcodes: H225,H304,H315,H336,H361f,H372,H411
• Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3