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695068

Hydrofluoric acid

ACS reagent, 48%

Synonym(s):

HF

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Size/SKUAvailabilityPrice
25 mL
Please contact Customer Service for Availability
$64.30
$54.65
500 mL
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$96.80

About This Item

Linear Formula:
HF
CAS Number:
Molecular Weight:
20.01
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
EC Number:
231-634-8
MDL number:
Assay:
48%
Form:
liquid
Grade:
ACS reagent

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grade

ACS reagent

Quality Segment

vapor density

1.27 (vs air)

vapor pressure

25 mmHg ( 20 °C)

assay

48%

form

liquid

impurities

≤0.5 ppm As (Arsenic), ≤0.5 ppm Pb (Lead)

density

1.15 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 ppm, phosphate (PO43-): ≤1 ppm, sulfate, sulfite (as SO42-): ≤5 ppm

cation traces

As: ≤0.05 ppm, Cu: ≤0.1 ppm, Fe: ≤1 ppm, heavy metals (as Pb): ≤0.5 ppm

SMILES string

[H+].[F-]

InChI

1S/FH/h1H

InChI key

KRHYYFGTRYWZRS-UHFFFAOYSA-N

General description

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. It is composed of hydrogen and fluoride. Hydrofluoric acid is a colorless and highly corrosive liquid. It is commonly used in the manufacture of hydrocarbons and polishing and conditioning glass. Additionally, it is used as a catalyst and in the synthesis of fluoride-containing compounds, and semiconductors.

Application

Hydrofluoric acid solution can be used as a reagent to synthesize:
  • Cyanohydrin alkyl ethers via chiral Bronsted acid-mediated hydrocyanation of vinyl ethers with silyl cyanides.
  • N, N-Dimethylaniline hydrochloride salts via Pd-catalyzed Buchwald-Hartwig amination of aryl triflates with dimethylamines.
It can also be used as a catalyst for the amidation of carboxylic acids with amines to synthesize amides.

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This Item
3392611.003341.00338
grade

ACS reagent

grade

-

grade

ACS reagent

grade

-

assay

48%

assay

≥99.99% trace metals basis

assay

-

assay

-

form

liquid

form

liquid

form

liquid

form

liquid

density

1.15 g/mL at 25 °C (lit.)

density

1.15 g/mL at 25 °C (lit.)

density

1.16 g/cm3 at 20 °C, 1.15 g/mL at 25 °C (lit.)

density

1.13 g/cm3 at 20 °C, 1.15 g/mL at 25 °C (lit.)

vapor pressure

25 mmHg ( 20 °C)

vapor pressure

25 mmHg ( 20 °C)

vapor pressure

25 mmHg ( 20 °C)

vapor pressure

25 mmHg ( 20 °C)

cation traces

As: ≤0.05 ppm, Fe: ≤1 ppm, Cu: ≤0.1 ppm, heavy metals (as Pb): ≤0.5 ppm

cation traces

-

cation traces

-

cation traces

-


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pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. Does the 500 ml bottle come with a top cap with a spout?

    1 answer
    1. This product is packaged in an HDPE bottle with a polypropylene screw cap. The cap has a PTFE liner. A pouring spout or ring in not included.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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