252964

Sigma-Aldrich

Diphenylphosphine

98%

Synonym(s):
HPPh2, Ph2PH
Linear Formula:
(C6H5)2PH
CAS Number:
Molecular Weight:
186.19
Beilstein/REAXYS Number:
742504
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

2 mmHg ( 110 °C)

Quality Level

assay

98%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.625 (lit.)

bp

280 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

C1(PC2=CC=CC=C2)=CC=CC=C1

InChI

1S/C12H11P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

InChI key

GPAYUJZHTULNBE-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Packaging

10 g in glass bottle
1 kg in Sure/Seal™
50 g in Sure/Seal™

Application

Deprotonation of Ph2PH gives diphenylphosphide, used for synthesis of novel phosphine ligands, Wittig-Horner reagents, and phosphonium salts; source of phosphorus-centered radicals.

pictograms

FlameExclamation mark

signalword

Danger

hazcat

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

storage_class_code

4.2 - Pyrophoric and self-heating hazardous materials

WGK Germany

WGK 3

Flash Point F

230.0 °F - closed cup

Flash Point C

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Posner, G. H.; Nelson, T. D.
The Journal of Organic Chemistry, 56, 4339-4339 (1991)
Brumwell, J. E.; Simpkins, N. S. et al.
Tetrahedron Letters, 34, 1215-1215 (1993)
Schow, S. R.; Bloom, J. D. et al.
Journal of the American Chemical Society, 108, 2662-2662 (1986)
Urszula K Komarnicka et al.
Journal of inorganic biochemistry, 165, 25-35 (2016-10-21)
In this paper we present lomefloxacin's (HLm, 2nd generation fluoroquinolone antibiotic agent) organic and inorganic derivatives: aminomethyl(diphenyl)phosphine (PLm), its oxide as well as new copper(I) iodide or copper(I) thiocyanate complexes with PLm and 2,9-dimethyl-1,10-phenanthroline (dmp) or 2,2'-biquinoline (bq) as the...
Yu Wang et al.
Science advances, 5(6), eaaw5623-eaaw5623 (2019-06-13)
The behavior of individual nanocrystals during superlattice phase transitions can profoundly affect the structural perfection and electronic properties of the resulting superlattices. However, details of nanocrystal morphological changes during superlattice phase transitions are largely unknown due to the lack of...

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service