343714

Sigma-Aldrich

Dichlorotris(1,10-phenanthroline)ruthenium(II) hydrate

98%

Synonym(s):
Tris(1,10-phenanthroline)ruthenium(II) chloride hydrate
Empirical Formula (Hill Notation):
C36H24Cl2N6Ru · xH2O
CAS Number:
Molecular Weight:
712.59 (anhydrous basis)
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

SMILES string

O.Cl[Ru]Cl.c1cnc2c(c1)ccc3cccnc23.c4cnc5c(c4)ccc6cccnc56.c7cnc8c(c7)ccc9cccnc89

InChI

1S/3C12H8N2.2ClH.H2O.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;;/h3*1-8H;2*1H;1H2;/q;;;;;;+2/p-2

InChI key

WGNGRGQLNAWTJI-UHFFFAOYSA-L

General description

The oxygen sensitivity and phototoxicity of [Ru(Phen)] in chicken embryo chorioallantoic membrane was investigated.

Application

Fluorescence quenching of dichloro(tris-1,10-phenanthroline) ruthenium (II) hydrate is is triggered by oxygen.1 (Ru(phen)3Cl2 may be used to imprint mesoporous molecular sieves (SBA-15).

Packaging

1 g in glass bottle

storage_class_code

11 - Combustible Solids

WGK Germany

WGK 3

Flash Point F

Not applicable

Flash Point C

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Molecular imprinting of mesoporous SBA-15 with chiral ruthenium complexes.
Coutinho D,et al
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 249-255 null
In vivo measurement of tissue oxygenation by time-resolved luminescence spectroscopy: advantageous properties of dichlorotris (1, 10-phenanthroline)-ruthenium (II) hydrate.
Huntosova V, et al.
Journal of Biomedical Optics null
In vivo measurement of tissue oxygenation by time-resolved luminescence spectroscopy: advantageous properties of dichlorotris (1, 10-phenanthroline)-ruthenium (II) hydrate.
Huntosova V, et al.
Journal of Biomedical Optics, 077004-077004 null
Oxygen sensor based on the fluorescence quenching of a ruthenium complex immobilized in a biocompatible poly (ethylene glycol) hydrogel.
O' Neal DP, et al.
Sensors null
Oxygen sensor based on the fluorescence quenching of a ruthenium complex immobilized in a biocompatible poly (ethylene glycol) hydrogel.
O' Neal DP, et al.
Sensors, 728-734 null

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service