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Merck

372331

Ammonium acetate

99.999% trace metals basis

Synonym(s):

Ammonium ethanoate

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10 G

CHF 108.00

100 G

CHF 486.00

1 KG

CHF 4’030.00

CHF 108.00


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About This Item

Linear Formula:
CH3CO2NH4
CAS Number:
Molecular Weight:
77.08
NACRES:
NA.23
PubChem Substance ID:
eCl@ss:
39021908
UNSPSC Code:
12352302
EC Number:
211-162-9
MDL number:
Beilstein/REAXYS Number:
4186741
Assay:
99.999% trace metals basis
Form:
crystalline
solid

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Product Name

Ammonium acetate, 99.999% trace metals basis

InChI key

USFZMSVCRYTOJT-UHFFFAOYSA-N

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

SMILES string

N.CC(O)=O

assay

99.999% trace metals basis

form

crystalline
solid

technique(s)

HPLC: suitable

impurities

≤20.0 ppm Trace Metal Analysis

mp

110-112 °C (dec.) (lit.)

Quality Level

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1 of 4

This Item
32301-M3230173594
form

crystalline, solid

form

solid

form

solid

form

solid

assay

99.999% trace metals basis

assay

≥98%

assay

≥98%

assay

≥99.0% (calc. on dry substance, T)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

mp

110-112 °C (dec.) (lit.)

mp

110-112 °C (dec.) (lit.)

mp

110-112 °C (dec.) (lit.)

mp

110-112 °C (dec.) (lit.)

impurities

≤20.0 ppm Trace Metal Analysis

impurities

≤0.0002% heavy metals (as Pb), ≤0.005% KMnO4 red. matter (as HCOOH), ≤2% water (Karl Fischer)

impurities

≤0.005% KMnO4 red. matter (as O), ≤2% water (Karl Fischer), ≤5 mg/kg heavy metals (as Pb)

impurities

insoluble matter, passes filter test, ≤1% water

technique(s)

HPLC: suitable

technique(s)

-

technique(s)

-

technique(s)

LC/MS: suitable

Application

Ammonium acetate can be used:
  • To passivate CsPbI3 perovskite nanocrystals for red LEDs. Ammonium acetate effectively eliminate undesired surface metallic lead cations and dangling bonds to enhance the stability and photoluminescence quantum yield (PLQY).
  • As an additive to fabricate high quality perovskite solar cell with enhanced power conversion efficiency (PCE) of 13.9%. It promotes crystallization and improve performance without changing the perovskite composition.
  • As a cost effective and green electrolyte for all-organic battery-supercapacitor hybrid device with maximum energy density.
  • As an electrolyte additive for aqueous zinc batteries. It helps to improve cycling stability and capacity retention.

General description

Ammonium acetate is a white crystalline water-soluble ammonium salt with unique properties that make it suitable for use in solar cells, batteries, and fuel cell catalysts.

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Anima Ghosal et al.
Drug metabolism and disposition: the biological fate of chemicals, 32(3), 314-320 (2004-02-24)
Ezetimibe [1-(4-fluorophenyl)-3(R)-[3-(4-fluorophenyl)-3(S)-hydroxypropyl]-4(S)-(4-hydroxyphenyl)-2-azetidinone] (Zetia; Schering-Plough, Kenilworth, NJ) is the first in a new class of cholesterol-lowering agents known as cholesterol absorption inhibitors. The objective of this study was to identify the isoform(s) of human liver and intestinal UDP-glucuronosyltransferase (UGT) enzymes responsible
Reactions of phenanthraquinone and retenequinone with aldehydes and ammonium acetate in acetic acid solution1.
Steck EA and Day AR.
Journal of the American Chemical Society, 65(3), 452-456 (1943)
Selective inhibition of benzyl ether hydrogenolysis with Pd/C due to the presence of ammonia, pyridine or ammonium acetate.
Sajiki H.
Tetrahedron Letters, 36(20), 3465-3468 (1995)
S Baron-Cohen et al.
Molecular psychiatry, 20(3), 369-376 (2014-06-04)
Autism affects males more than females, giving rise to the idea that the influence of steroid hormones on early fetal brain development may be one important early biological risk factor. Utilizing the Danish Historic Birth Cohort and Danish Psychiatric Central
Shi Hu et al.
Oncotarget, 6(3), 1695-1706 (2015-01-31)
Human epidermal growth factor receptors (HERs or ErbBs) play crucial roles in numerous cellular processes. ErbB2 is a key member of ErbB family, and its overexpression is recognized as a frequent molecular abnormality. In cancer, this overexpression correlates with aggressive

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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