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Merck

912727

Sigma-Aldrich

(2R,3R)-iPr-BIDIME

Synonym(s):

(2R,3R)-3-(Tert-butyl)-4-(2,6-dimethoxyphenyl)-2-isopropyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

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250 MG
CHF 288.00

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250 MG
CHF 288.00

About This Item

Empirical Formula (Hill Notation):
C22H29O3P
CAS Number:
Molecular Weight:
372.44
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22

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CHF 288.00


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form

powder and chunks

Quality Level

optical purity

ee: ≥99% (HPLC)

reaction suitability

reagent type: ligand

functional group

phosphine

SMILES string

P1([C@@H](Oc2c1c(ccc2)c3c(cccc3OC)OC)C(C)C)C(C)(C)C

InChI

1S/C22H29O3P/c1-14(2)21-25-18-13-8-10-15(20(18)26(21)22(3,4)5)19-16(23-6)11-9-12-17(19)24-7/h8-14,21H,1-7H3/t21-,26?/m1/s1

InChI key

AVUPKIFOTAYCAC-OSMGYRLQSA-N

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This Item
913200912956912719
reaction suitability

reagent type: ligand

reaction suitability

reagent type: ligand

reaction suitability

reagent type: ligand

reaction suitability

reagent type: ligand

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

powder and chunks

form

powder

form

powder

form

powder

optical purity

ee: ≥99% (HPLC)

optical purity

ee: ≥99% (HPLC)

optical purity

ee: ≥99% (HPLC)

optical purity

ee: ≥99% (HPLC)

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Application

(2R,3R)-iPr-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.

Legal Information

Sold in collaboration with Zejun Pharmaceuticals

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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