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09859

Sigma-Aldrich

Ammonium hydroxide solution

BioUltra, ~1 M NH3 in H2O (T)

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Synonym(s):
Ammonia aqueous, Ammonia water
Linear Formula:
NH4OH
CAS Number:
1336-21-6
Molecular Weight:
35.05
Beilstein:
3587154
MDL number:
MFCD00066650
eCl@ss:
38060103
PubChem Substance ID:
329748850
NACRES:
NA.25

product line

BioUltra

Quality Level

200

form

liquid

expl. lim.

27 %

concentration

~1 M NH3 in H2O (T)

impurities

insoluble matter, passes filter test

density

0.9 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.5 mg/kg
phosphate (PO43-): ≤0.5 mg/kg
sulfate (SO42-): ≤2 mg/kg

cation traces

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

λ

neat

UV absorption

λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01

storage temp.

2-8°C

SMILES string

[NH4+].[OH-]

InChI

1S/H3N.H2O/h1H3;1H2

InChI key

VHUUQVKOLVNVRT-UHFFFAOYSA-N

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This Item
1.054281.054231.05426
Ammonium hydroxide solution BioUltra, ~1 M NH3 in H2O (T)

Sigma-Aldrich

09859

Ammonium hydroxide solution

Ammonia solution 25 % Suprapur®

Supelco

1.05428

Ammonia solution 25 %

Ammonia solution 28-30% for analysis EMSURE® ACS,Reag. Ph Eur

Supelco

1.05423

Ammonia solution 28-30%

Ammonia solution 32% EMPLURA®

Supelco

1.05426

Ammonia solution 32%

concentration

~1 M NH3 in H2O (T)

concentration

25%

concentration

28.0-30.0% NH4OH

concentration

≥30% (NH3, acidimetric)

impurities

insoluble matter, passes filter test

impurities

-

impurities

≤0.020 ppm Ag (Silver), ≤0.020 ppm Ga (Gallium), ≤0.020 ppm In (Indium), ≤0.020 ppm Li (Lithium), ≤0.050 ppm Ba (Barium), ≤0.050 ppm Cd (Cadmium), ≤0.050 ppm Co (Cobalt), ≤0.050 ppm Cr (Chromium), ≤0.050 ppm Mn (Manganese), ≤0.050 ppm Mo (Molybdenum), ≤0.050 ppm Ni (Nickel), ≤0.050 ppm Pb (Lead), ≤0.050 ppm Tl (Thallium), ≤0.100 ppm Au (Gold), ≤0.100 ppm Bi (Bismuth), ≤0.100 ppm Cu (Copper), ≤0.100 ppm Fe (Iron), ≤0.100 ppm Mg (Magnesium), ≤0.100 ppm Pt (Platinum), ≤0.100 ppm Sn (Tin), ≤0.100 ppm Sr (Strontium), ≤0.100 ppm Ti (Titanium), ≤0.100 ppm Zn (Zinc), ≤0.2 ppm Sulphide (S), ≤0.3 ppm Chloride (Cl), ≤0.5 ppm Heavy metals (as Pb), ≤0.5 ppm Phosphate (PO4), ≤0.500 ppm Al (Aluminium), ≤0.500 ppm As (Arsenic), ≤0.500 ppm Ca (Calcium), ≤0.500 ppm K (Potassium), ≤0.500 ppm Na (Sodium), ≤10 ppm Carbonate (as CO2), ≤10 ppm Non volatile matter, ≤2 ppm Nitrate (NO3), ≤2 ppm Pyridine and related substances, ≤2 ppm Sulphate (SO4), ≤5 ppm Silicate (as SiO2), ≤5 ppm Substances reducing potassium permanganate

impurities

≤0.0001% Heavy metals (as Pb), ≤0.0005% Fe (Iron), ≤0.0008% Substances reducing potassium permanganate (as O), ≤0.002% Chloride (Cl), ≤0.003% Sulphate (SO?)

density

0.9 g/mL at 25 °C (lit.)

density

0.9 g/mL at 25 °C (lit.)

density

0.9 g/mL at 25 °C (lit.), 0.892-0.910 (relative density (d 20/20))

density

0.9 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.5 mg/kg, phosphate (PO43-): ≤0.5 mg/kg, sulfate (SO42-): ≤2 mg/kg

anion traces

-

anion traces

-

anion traces

-

cation traces

Al: ≤1 mg/kg, As: ≤0.1 mg/kg, Ba: ≤1 mg/kg, Bi: ≤1 mg/kg, Ca: ≤5 mg/kg, Cd: ≤1 mg/kg, Co: ≤1 mg/kg, Cr: ≤1 mg/kg, Cu: ≤1 mg/kg, Fe: ≤1 mg/kg, K: ≤20 mg/kg, Li: ≤1 mg/kg, Mg: ≤1 mg/kg, Mn: ≤1 mg/kg, Mo: ≤1 mg/kg, Na: ≤20 mg/kg, Ni: ≤1 mg/kg, Pb: ≤1 mg/kg, Sr: ≤1 mg/kg, Zn: ≤1 mg/kg

cation traces

-

cation traces

-

cation traces

-

Application

Ammonium hydroxide solution can be used to study chromatography, base solutions, analytical reagents, titration and volumetric solutions. Ammonium hydroxide solution has been used to develop a single-laboratory validation by inductively coupled plasma-mass spectrometry for the determination of total iodine (m/z 127) in infant formula and adult nutritional products. Ammonium hydroxide solution has also been used to develop a sensitive liquid chromatography-tandem mass spectrometry method to quantify miglustat in mouse plasma and in human plasma, which has improved treatment of patients with cystic fibrosis.

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H315 - H318 - H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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