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Merck

33517

Sigma-Aldrich

Phenol

ACS reagent grade, 99.5-100.5% (GC), 99.0-100.5%, solid, puriss. p.a., reag. Ph. Eur.

Synonym(s):

Hydroxybenzene

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CHF 72.20
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CHF 124.00
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CHF 228.00
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100 G
CHF 72.20
500 G
CHF 124.00
1 KG
CHF 228.00
6 X 1 KG
CHF 788.00

About This Item

Linear Formula:
C6H5OH
CAS Number:
Molecular Weight:
94.11
Beilstein:
969616
EC Number:
MDL number:
UNSPSC Code:
12352104
PubChem Substance ID:
NACRES:
NA.21

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CHF 72.20


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Product Name

Phenol, puriss. p.a., ACS reagent, reag. Ph. Eur., 99.0-100.5%

grade

ACS reagent
puriss. p.a.

Quality Level

Agency

reag. Ph. Eur.

vapor density

3.24 (vs air)

vapor pressure

0.09 psi ( 55 °C)
0.36 mmHg ( 20 °C)

Assay

99.0-100.5%
99.5-100.5% (GC)

form

solid

autoignition temp.

1319 °F

expl. lim.

8.6 %

impurities

≤0.001% heavy metals (as Pb)
≤0.01% non-volatile matter
≤0.05% m-cresol (GC)
≤0.05% o-cresol (GC)
≤0.05% p-cresol (GC)
≤0.2% water (Karl Fischer)

bp

180-181 °C
182 °C (lit.)

mp

40-42 °C (lit.)

transition temp

solidification point ≥40.5 °C

density

1.071 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 mg/kg

cation traces

Fe: ≤1 mg/kg

SMILES string

Oc1ccccc1

InChI

1S/C6H6O/c7-6-4-2-1-3-5-6/h1-5,7H

InChI key

ISWSIDIOOBJBQZ-UHFFFAOYSA-N

Gene Information

human ... GABRA1(2554)

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Show Differences

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This Item
P55667760835952
Phenol puriss. p.a., ACS reagent, reag. Ph. Eur., 99.0-100.5%

33517

Phenol

Phenol BioXtra, ≥99.5% (GC)

P5566

Phenol

Phenol BioUltra, Molecular Biology, ≥99.5% (GC)

77608

Phenol

Phenol PESTANAL®, analytical standard

35952

Phenol

assay

99.0-100.5%, 99.5-100.5% (GC)

assay

≥99.5% (GC)

assay

≥99.5% (GC)

assay

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

density

1.071 g/mL at 25 °C (lit.)

density

1.071 g/mL at 25 °C (lit.)

density

1.071 g/mL at 25 °C (lit.)

density

1.071 g/mL at 25 °C (lit.)

form

solid

form

powder

form

solid

form

-

bp

180-181 °C, 182 °C (lit.)

bp

182 °C (lit.)

bp

182 °C (lit.)

bp

182 °C (lit.)

mp

40-42 °C (lit.)

mp

40-42 °C (lit.)

mp

40-42 °C (lit.)

mp

40-42 °C (lit.)

General description

Oxidation of phenol at synthetic boron-doped diamond thin film electrode (BDD) in perchloric acid medium has been proposed.[1] Mechanism of its oxidation to afford oxygen at doped SnO2 coated titanium anodes has been investigated.[2] Various industrial processes for the synthesis of phenol have been described.[3]

Application

Phenol may be used in the preparation of phenol reagents which participates in the Berthelot color reaction for the quantification of ammonia.[4] It may be used in the preparation of cresols, via Friedel-Crafts alkylation reaction.[3]

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - STOT RE 2

Target Organs

Nervous system,Kidney,Liver,Skin

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

177.8 °F - closed cup

Flash Point(C)

81 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. What is the process you use to synthesize this phenol? I am interested in obtaining phenols with different oxygen isotopic compositions, so I would like to know where the oxygen is coming from.

    1 answer
    1. Unfortuantely, the synthesis process is considered proprietary.

      Helpful?

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