Skip to Content
Merck

Skip To

179337

Methanol

≥99.8%, ACS reagent, suitable for EPA 1613

Methanol

Synonym(s):

Methyl alcohol

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Pack SizeSKUAvailabilityPrice

About This Item

Linear Formula:
CH3OH
CAS Number:
Molecular Weight:
32.04
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39020101
UNSPSC Code:
12352104
EC Number:
200-659-6
MDL number:
Beilstein/REAXYS Number:
1098229
Assay:
≥99.8%
Grade:
ACS reagent
Bp:
64.7 °C (lit.)
Vapor pressure:
410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)
Pricing and availability is not currently available.
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Product Name

Methanol, ACS reagent, ≥99.8%

grade

ACS reagent

Quality Level

agency

suitable for EPA 1613

vapor density

1.11 (vs air)

vapor pressure

410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

autoignition temp.

725 °F

expl. lim.

36 %

dilution

(for analytical testing)

impurities

H2SO4, passes test (darkened), MnO4- reducers, passes test, ≤0.0002 meq/g Titr. base, ≤0.0003 meq/g Titr. acid, ≤0.001% acetaldehyde, ≤0.001% acetone, ≤0.001% formaldehyde, ≤0.1% water

evapn. residue

≤0.001%

color

APHA: ≤10, clear

refractive index

n20/D 1.329 (lit.)

bp

64.7 °C (lit.)

mp

−98 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

format

neat

SMILES string

CO

InChI

1S/CH4O/c1-2/h2H,1H3

InChI key

OKKJLVBELUTLKV-UHFFFAOYSA-N

General description

Methanol is an organic solvent that can be synthesized from syngas in the presence of CuO/ZnO/Al2O3 catalysts. It is an ideal candidate as a hydrogen source in fuel cell technology due to its high H/C ratio, low propensity for soot generation, relatively low reforming temperature and as it exists in liquid state at room temperature. In a direct methanol fuel cell (DMFC), methanol undergoes oxidation with air to generate electricity. The olefins (ethylene or propylene) formed from methanol via MTO (methanol-to-olefins) process, can be an alternative to oil and gas to produce hydrocarbon fuels.
Methanol undergoes thermochemical conversion to C2-C10 hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

Application

Methanol has been used as a solvent for the sodium dodecyl sulfate-polyacrylamide gel electrophoretic (SDS-PAGE) analysis of alkaline protease isoforms isolated from larva of the spotted sand bass (Paralabrax maculatofasciatus). It has been used in the isolation and quantitative determination of carotenes and xanthophylls from Capsicum annum pericarp extracts by HPLC.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
179957439193494437
Quality Level

100, 200

Quality Level

100

Quality Level

100

Quality Level

100

assay

≥99.8%

assay

≥99.6%

assay

≥99.9%

assay

≥99.93%

grade

ACS reagent

grade

Laboratory Reagent

grade

gradient grade

grade

-

form

liquid

form

liquid

form

-

form

-

mp

−98 °C (lit.)

mp

−98 °C (lit.)

mp

−98 °C (lit.)

mp

−98 °C (lit.)

vapor density

1.11 (vs air)

vapor density

1.11 (vs air)

vapor density

1.11 (vs air)

vapor density

1.11 (vs air)


Still not finding the right product?

Explore all of our products under Methanol


signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

49.5 °F - closed cup

flash_point_c

9.7 °C - closed cup



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library


Related Content

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.


Beyond oil and gas: the methanol economy.
Olah GA.
Angewandte Chemie (International Edition in English), 44(18) (2005)
Development of digestive enzyme activity in larvae of spotted sand bass Paralabrax maculatofasciatus II: electrophoretic analysis.
Alvarez-Gonzalez CA, et al.
Fish Physiology and Biochemistry, 36(1), 29-37 (2010)
Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies.
Jadhav SG, et al.
Chemical Engineering Research and Design, 92(11), 2557-2567 (2014)



Global Trade Item Number

SKUGTIN
179337-18L-CS04061838754172
179337-2.5L04061837565083
179337-200L-LSNBOR04061838151384
179337-4X4L04061837565120
179337-6X1L04061837565144
179337-4X2.5L04061837565113
179337-500ML04061837565137
179337DS-270GA04061838161130
179337-20L04061837909542
179337-4L04061837565106
179337-4X4L-PB04061838754189
179337-56L-P1-OR04061838689900
179337-VB-200LP1SB04065268977743
179337-1L04061837565076

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. Is this methanol HPLC grade?

    1 answer
    1. This product has not been tested specifically for use in HPLC. The purity of this material is determined by GC. There are a number of HPLC qualified products available. Please see the link below to review these options:
      https://www.sigmaaldrich.com/search/methanol-suitable-for-hplc?focus=products&page=1&perpage=30&sort=relevance&term=methanol%20suitable%20for%20HPLC&type=product

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

Active Filters

  1. 1 Ratings-only review