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117854

Trioctylphosphine

greener alternative

Greener Alternative

technical grade, 90%

Synonym(s):

TOP, P(Oct)3

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Size/SKUAvailabilityPrice
4 x 25 mL

Available to ship TODAYfromSchnelldorf

€115.00
100 mL

Available to ship TODAYfromSchnelldorf

€165.00
500 mL

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€719.00
2.5 L
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€1,870.00

About This Item

Linear Formula:
[CH3(CH2)7]3P
CAS Number:
Molecular Weight:
370.64
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-234-2
Beilstein/REAXYS Number:
1776995
MDL number:

€115.00


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grade

technical grade

assay

90%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

density

0.831 g/mL at 25 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

RMZAYIKUYWXQPB-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This ligand facilitates quantum dot and metal nanoparticle formation with precise size and morphology control. As a phosphorus source for low-temperature metal phosphide conversion, it enables scalable nanomaterial production with reduced energy consumption. Click here for more information.

Application

Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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description

technical grade, 90%

description

97%

description

97%

description

ReagentPlus®, 99%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling

reaction suitability

reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction

reaction suitability

reagent type: ligand
reaction type: Negishi Coupling, reaction type: Silylations, reaction type: Cross Couplings, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reagent type: ligand, reaction type: Stille Coupling

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

density

0.831 g/mL at 25 °C (lit.)

density

0.831 g/mL at 25 °C (lit.)

density

-

density

-

bp

284-291 °C/50 mmHg (lit.)

bp

284-291 °C/50 mmHg (lit.)

bp

-

bp

201-202 °C/2 mmHg (lit.)

grade

technical grade

grade

-

grade

-

grade

-

refractive index

n20/D 1.468 (lit.)

refractive index

n20/D 1.468 (lit.)

refractive index

-

refractive index

-


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

296.6 °F - closed cup

flash_point_c

147 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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