Merck
All Photos(2)

693383

Sigma-Aldrich

cBRIDP

greener alternative
Synonym(s):
Di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine, Mo-Phos
Empirical Formula (Hill Notation):
C24H33P
CAS Number:
Molecular Weight:
352.49
MDL number:
PubChem Substance ID:

Quality Level

form

crystals

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

87-91 °C

functional group

phosphine

greener alternative category

SMILES string

CC(C)(C)P(C(C)(C)C)C1(C)CC1(c2ccccc2)c3ccccc3

InChI

1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3

InChI key

QMLPJDVGNRHGJQ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

Application

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

Packaging

100, 500 mg in glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only.

Certificate of Analysis

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Certificate of Origin

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More Documents

Quotes and Ordering

Articles

Procedures for Transition-Metal-Catalyzed Cross-Coupling Reactions in Water at Room Temperature using TPGS-750-M

TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Protocols

Buchwald-Hartwig Amination Reaction in Water at Room Temperature using TPGS-750-M

Buchwald-Hartwig Amination Reaction in Water at Room Temperature using TPGS-750-M

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