Merck
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747599

Sigma-Aldrich

Boxed reaction: Buchwald-Hartwig in Lipshutz Surfactant

greener alternative
NACRES:
NA.22

Quality Level

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Waste Prevention
Designing Safer Chemicals
Design for Energy Efficiency
Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative category

Aligned

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

This kit contains the reagents, catalyst, and solvent required to perform a Buchwald-Hartwig reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol for details.

Packaging

1 kit in ampule

Kit Components Also Available Separately

Product No.
Description
SDS

  • 156671Potassium tert-butoxide, reagent grade, ≥98% 180 mg

  • 222380Allylpalladium(II) chloride dimer, 98% 5 mg

  • 693383cBRIDP 8 mg

  • 733857DL-α-Tocopherol methoxypolyethylene glycol succinate solution, 2 wt. % in H2O 1 mL

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 2 - Skin Corr. 1A - Water-react. 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 3

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

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