Merck
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249866

Sigma-Aldrich

Titanium(IV) chloride solution

1.0 M in methylene chloride

Synonym(s):
Titanium tetrachloride
Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
MDL number:
PubChem Substance ID:
NACRES:
NA.55

vapor pressure

24.09 psi ( 55 °C)
6.93 psi ( 20 °C)

Quality Level

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride

density

1.365 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Packaging

100, 4×100, 800 mL in Sure/Seal™

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificate of Analysis

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Certificate of Origin

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