Skip to Content
Merck

Silicone Materials

Representative chemical structure of polysiloxane, commonly known as silicone and silicone oil

SILICONES

Silicones, also known as polysiloxanes, are synthetic polymers with a silicon-oxygen backbone like that in silicon dioxide but containing additional organic groups. Unlike homologous carbon-based polymers, these compounds show a unique combination of physical and chemical properties due to the exceptional physicochemical properties of the siloxane (-Si-O-) bond. Silicone-containing copolymers and silicone-modified networks have extremely high backbone flexibility and very low glass transition temperatures (Tg), around −120 °C. They also demonstrate good thermal and oxidative stability, high gas permeability, excellent dielectric properties, biocompatibility, and minimal surface tension.


Products

201 - 300 (1)

301 - 400 (1)

501 - 600 (1)

601 - 700 (1)

701 - 800 (1)

801 - 900 (2)

101 - 200 (7)

201 - 300 (3)

301 - 400 (3)

aliphatic functional groups (12)

CHO containing functional groups (7)

CHN containing functional groups (2)

heterocyclic - 1 ring (2)

aromatic hydrocarbons (1)

sulfur containing functional groups (1)
Sort by Relevance
Showing 1-20 of 42
Change View
Showing 1-20 of 42
Silicone oil
317667

Silicone oil

viscosity 5 cSt (25 °C)

SYLGARD<SUP>®</SUP> 184
761036

SYLGARD® 184

10 g clip-pack

Silicone oil
378321

Silicone oil

viscosity 10 cSt (25 °C)

Silicone oil
85409

Silicone oil

for oil baths (from -50°C to +200°C)

Silicone oil
378364

Silicone oil

viscosity 100 cSt (25 °C)

SYLGARD<SUP>®</SUP> 184
761028

SYLGARD® 184

5 g clip-pack

Silicone oil
378348

Silicone oil

viscosity 20 cSt (25 °C)

Silicone oil
378399

Silicone oil

viscosity 1,000 cSt (25 °C)

Silicone oil AR 20
10836

Silicone oil

AR 20, viscosity ~20 mPa.s,   neat(25 °C)

Silicone oil
378356

Silicone oil

viscosity 50 cSt (25 °C)

Silicone oil
378380

Silicone oil

viscosity 500 cSt (25 °C)

Silicone oil
378372

Silicone oil

viscosity 350 cSt (25 °C)

Silicone oil
378402

Silicone oil

viscosity 10,000 cSt (25 °C)

SYLGARD<SUP>®</SUP> 170 silicone elastomer
805998

SYLGARD® 170 silicone elastomer

10 cc dual syringe with the static mixer

Silicone oil
175633

Silicone oil

for oil baths (from -40°C to +230°C)

Silicone oil AP 150
50384

Silicone oil

AP 150, viscosity ~150 mPa.s,   neat(25 °C)

Silicone oil AP 100
10838

Silicone oil

AP 100, viscosity ~100 mPa.s,   neat(25 °C)

Silicone oil AP 1000
10842

Silicone oil

AP 1000, viscosity ~1000 mPa.s,   neat(25 °C)

Silicone oil
181838

Silicone oil

viscosity 60,000 cSt (25 °C)

Dow Corning<SUP>®</SUP> 736 heat resistant sealant
804002

Dow Corning® 736 heat resistant sealant

You have viewed 1-20 of 42 results

CLASSIFICATION OF SILICONES

Our silicone (polysiloxane) silicone polymers demonstrate a variety of silicone material properties and can be categorized as fluids, elastomers, or resins. Polymers of moderate molecular weight are classified as fluids, while slightly cross-linked polymers with high molecular weight are elastomeric. Low molecular weight resins contain functional groups, usually hydroxyl, alkoxy, or chloro groups, that undergo hydrolysis and/or condensation to form highly cross-linked structures.

Common silicone material science applications of our basic products include:

  • Silicone elastomers, such as polydimethylsiloxane (PDMS), for patterned stamps in soft lithography and nano-pattering applications
  • Dielectric materials for electrostatic actuators and dielectric energy harvesters
  • Encapsulation and packaging materials for electronic devices
  • Surface property modifying reagents for microfluidic applications

SILICONE COPOLYMERS AND HOMOPOLYMERS

Silicone co- and homopolymers form a hydrophobic surface with low water uptake and are primarily used in the preparation of lubricants, foams, and polymeric adhesives.

Silicones in our catalog have:

  • Non-reactive substitutes that tune the mechanical and thermal-mechanical properties (such as glass transition temperature)
  • Reactive substitutes and terminal groups to allow chemical modification (such as crosslinking)
  • Varying molecular weights and viscosity levels.

SILICONE OILS

Our catalog includes silicone oils (or silicone fluids) which are any liquid polymerized siloxane having organic side chains. They are more thermodynamically stable than other siloxanes due to a highly polarized Si‐O‐Si bond with a large bond energy. Silicone fluids exhibit greater structural flexibility, permeability, and lubricity due to freely rotating methyl groups as well as weak intermolecular attractive forces. Furthermore, they have excellent wetting and film-forming properties due to lower surface tension and are odorless, non‐toxic, water-repellent, chemical-resistant, and UV-resistant.

We offer a wide range of silicone oils with various degrees of viscosity, spanning from 5 c St (or 5 mPa∙s) to 100,000 c St (or 100,000 mPa∙s) at 25 ˚C. Our silicone oils can be used as heating and cooling fluids in thermal management. When used in water/oil systems, our siloxanes generate stable emulsions of microdroplets which are widely used in DNA and blood analysis, chemical reactions, drug discovery, ink formulations, cosmetics, textiles, and home care products.


Related Resources



Sign In To Continue

To continue reading please sign in or create an account.

Don't Have An Account?