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  • Evaluation of potential for reuse of industrial wastewater using metal-immobilized catalysts and reverse osmosis.

Evaluation of potential for reuse of industrial wastewater using metal-immobilized catalysts and reverse osmosis.

Chemosphere (2014-12-31)
Jeongyun Choi, Jinwook Chung
ABSTRACT

This report describes a novel technology of reusing the wastewater discharged from the display manufacturing industry through an advanced oxidation process (AOP) with a metal-immobilized catalyst and reverse osmosis (RO) in the pilot scale. The reclaimed water generated from the etching and cleaning processes in display manufacturing facilities was low-strength organic wastewater and was required to be recycled to secure a water source. For the reuse of reclaimed water to ultrapure water (UPW), a combination of solid-phase AOP and RO was implemented. The removal efficiency of TOC by solid-phase AOP and RO was 92%. Specifically, the optimal acid, pH, and H2O2 concentrations in the solid-phase AOP were determined. With regard to water quality and operating costs, the combination of solid-phase AOP and RO was superior to activated carbon/RO and ultraviolet AOP/anion polisher/coal carbon.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Ethanol, absolute, sales not in Germany, ≥99.8% (vol.)
Supelco
Acetaldehyde, PESTANAL®, analytical standard
Sigma-Aldrich
Acetaldehyde, ACS reagent, ≥99.5%
Sigma-Aldrich
Ethanol, purum, secunda spirit, denaturated with 2% 2-butanone, S15, ~96% (based on denaturant-free substance)
Sigma-Aldrich
Acetaldehyde, ReagentPlus®, ≥99.0% (GC)
Supelco
Ethanol, standard for GC
Sigma-Aldrich
Acetaldehyde, puriss. p.a., anhydrous, ≥99.5% (GC)
Sigma-Aldrich
Ethanol
Sigma-Aldrich
Acetaldehyde, natural, FG
Sigma-Aldrich
Ethanol, tested according to Ph. Eur.
Sigma-Aldrich
Ethanol, purum, absolute ethanol, denaturated with 4.8% isopropanol, A15 IPA1, ≥99.8% (based on denaturant-free substance)
Sigma-Aldrich
Ethanol, BioUltra, Molecular Biology, ≥99.8%, (absolute alcohol, without additive, A15 o1)
USP
Methyl alcohol, United States Pharmacopeia (USP) Reference Standard
Sigma-Aldrich
Ethyl alcohol, Pure, 200 proof, meets USP testing specifications
Sigma-Aldrich
Ethyl alcohol, Pure, 200 proof, ACS reagent, ≥99.5%
Sigma-Aldrich
Ethanol, purum, absolute ethanol, denaturated with 2% 2-butanone, A15 MEK1, ≥99.8% (based on denaturant-free substance)
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Ethanol, purum, fine spirit, denaturated with 2% 2-butanone, F25 MEK1, ~96% (based on denaturant-free substance)
Sigma-Aldrich
Ethanol, purum, fine spirit, denaturated with 4.8% methanol, F25 METHYL1, ~96% (based on denaturant-free substance)
Sigma-Aldrich
Ethyl alcohol, Pure 200 proof, Molecular Biology
Sigma-Aldrich
Methanol, suitable for NMR (reference standard)
Sigma-Aldrich
Acetaldehyde solution, natural, 50 wt. % ethanol, FG
Sigma-Aldrich
Acetaldehyde solution, 50 wt. % in ethanol
Sigma-Aldrich
Acetone, ≥99%, FCC, FG
Sigma-Aldrich
Acetone, natural, ≥97%
Sigma-Aldrich
Acetaldehyde solution, 40 wt. % in isopropanol
Supelco
Ethanol solution, certified reference material, 2000 μg/mL in methanol
Sigma-Aldrich
Acetaldehyde solution, 40 wt. % in H2O
Sigma-Aldrich
Acetaldehyde solution, 5 M in THF
Millipore
Hydrogen peroxide solution, 3%, suitable for microbiology
Supelco
Hydrogen peroxide solution, ≥30%, for trace analysis