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732117

Pd-PEPPSI-IPent catalyst

≥95%, solid

Pd-PEPPSI™-IPent catalyst

Sinónimos:

Dichloro[1,3-bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II), [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)dichloropalladium(II), [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride

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A ustedes/SKUDisponibilidadPrecio
250 mg
Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad
206,00 €
1 g

Disponible para enviar HOYdesdeLyon

410,00 €
5 g
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1850,00 €
50 g
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16.410,00 €

Acerca de este artículo

Fórmula empírica (notación de Hill):
C40H56Cl3N3Pd
Número CAS:
Peso molecular:
791.67
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

206,00 €


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Nombre del producto

Pd-PEPPSI-IPent catalyst, ≥95%

Quality Segment

assay

≥95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium

mp

195-201 °C

functional group

NHC

storage temp.

−20°C

SMILES string

Clc1cccnc1.CCC(CC)c2cccc(C(CC)CC)c2N3C=CN(c4c(cccc4C(CC)CC)C(CC)CC)\C3=[Pd](/Cl)Cl

InChI

1S/C35H52N2.C5H4ClN.2ClH.Pd/c1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;6-5-2-1-3-7-4-5;;;/h17-24,26-29H,9-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChI key

BCXSKTXOKALLAZ-UHFFFAOYSA-L

General description

Pd-PEPPSI-IPent catalyst is a palladium-based catalyst used in cross-coupling reactions to form C-N and C- C bonds.

Application

  • Catalyst for Stille coupling reaction[1] (eq. 1)
  • Catalyst for Negishi coupling reaction[2] (eq. 2)
  • Catalyst for Suzuki coupling reaction[3] (eq. 3)
Reaction scheme for Pd catalyst PEPPSI<SUP>™</SUP>-IPent used in cross coupling reaction
For small scale and high throughput uses, product is also available as ChemBeads (928399)

Legal Information

Patented, U.S. Pat. No. 7,250,510. Sold under an exclusive license from Total Synthesis Ltd.
PEPPSI is a trademark of Total Synthesis Ltd.

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Este artículo
928399669032674702
assay

≥95%

assay

~5 wt.% loading of catalyst

assay

98%

assay

-

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst
core: palladium, reaction type: Cross Couplings, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling

reaction suitability

-

reaction suitability

-

reaction suitability

-

functional group

NHC

functional group

-

functional group

NHC

functional group

-

form

solid

form

solid

form

-

form

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

-


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Preguntas

1–2 de 2 Preguntas  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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