Merck
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156256

Sigma-Aldrich

Sodium methoxide solution

25 wt. % in methanol

Synonym(s):
Sodium methylate
Linear Formula:
CH3ONa
CAS Number:
Molecular Weight:
54.02
Beilstein:
3592982
Número MDL:
ID de la sustancia en PubChem:
NACRES:
NA.21

densidad de vapor

1.1 (vs air)

Nivel de calidad

200

presión de vapor

50 mmHg ( 20 °C)
96 mmHg ( 25 °C)

formulario

liquid

temp. de autoignición

878 °F

concentración

25 wt. % in methanol

índice de refracción

n20/D 1.37

densidad

0.945 g/mL at 25 °C

SMILES string

[Na+].C[O-]

InChI

1S/CH3O.Na/c1-2;/h1H3;/q-1;+1

InChI key

WQDUMFSSJAZKTM-UHFFFAOYSA-N

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Descripción general

The product is 25wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.

Aplicación

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.
Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).

Envase

25 mL in glass bottle
1, 2.5 L in glass bottle
18 L in steel drum

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Self-heat. 1 - Skin Corr. 1A - STOT SE 1

Órganos de actuación

Eyes

Riesgos supl.

Código de clase de almacenamiento

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 2

Punto de inflamabilidad F

51.8 °F - closed cup - Solvent

Punto de inflamabilidad C

11 °C - closed cup - Solvent


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificate of Analysis

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Certificate of Origin

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