Merck
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270997

Sigma-Aldrich

Dichloromethane

anhydrous, ≥99.8%, contains 40-150 ppm amylene as stabilizer

Sinónimos:
Methylene chloride, DCM
Empirical Formula (Hill Notation):
CH2Cl2
Número de CAS:
Peso molecular:
84.93
Beilstein:
1730800
Número de EC:
Número MDL:
ID de la sustancia en PubChem:
NACRES:
NA.21

Nivel de calidad

200

grado

anhydrous

densidad de vapor

2.9 (vs air)

presión de vapor

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)
6.86 psi ( 20 °C)

ensayo

≥99.8%

formulario

liquid

temp. de autoignición

1223 °F

contiene

40-150 ppm amylene as stabilizer

lim. expl.

22 %

technique(s)

gas chromatography (GC): suitable

impurezas

≤0.001% water
≤0.005% water (100 mL pkg)

residuo de evap.

<0.0005%

índice de refracción

n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−97 °C (lit.)

densidad

1.325 g/mL at 25 °C (lit.)

SMILES string

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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Descripción general

Dichloromethane has been tested as a solvent medium for the dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. Role of quantity of TiO2 loading on activated carbon support employed in the photodecomposition of dichloromethane has been investigated.
Dichloromethane is a chlorinated organic solvent that is susceptible to degradation with time. This can be suppressed by adding amylene as a stabilizer.

Aplicación

Dichloromethane has been used for the quantification of herbivore (gypsy moth) induced blueberry volatiles by gas chromatography (GC).
Dichloromethane may be used as a solvent for the oxidation of primary and secondary alcohols using dipyridine-chromium(VI) oxide. Lithium perchlorate suspended in DCM is an effective medium for Mukaiyama aldol reactions of aldehydes with silyl ketene acetal. DCM may also be used as solvent for the synthesis of 2-bromo-6-lithiopyridine from 2,6-dibromopyridine via lithium-bromine exchange reaction.

Envase

1, 6×1, 2, 4×2 L in Sure/Seal™
20 L in Pure-Pac™ 2
100, 12×100 mL in Sure/Seal™
200 L in Pure-Pac™ 1
18 L in Pure-Pac™ 1

pictogramas

Exclamation markHealth hazard

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Punto de inflamabilidad F

does not flash

Punto de inflamabilidad C

does not flash

Equipo de protección personal

Eyeshields, Faceshields, Gloves

Certificado de Análisis

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Certificado de origen

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Cesar R Rodriguez-Saona
Journal of visualized experiments : JoVE, (58)(58), doi:10-doi:10 (2012-01-05)
Herbivore-induced plant volatiles (HIPVs) are commonly emitted from plants after herbivore attack. These HIPVs are mainly regulated by the defensive plant hormone jasmonic acid (JA) and its volatile derivative methyl jasmonate (MeJA). Over the past 3 decades researchers have documented
Carbon-carbon bond formation catalyzed by lithium perchlorate in dichloromethane
Reetz MT & Fox DN
Tetrahedron Letters, 34(7), 1119-1122 (1993)
Efficient Preparation of 2-Bromo-6-lithiopyridine via Lithium? Bromine Exchange in Dichloromethane
Peterson MA & Mitchell JR
The Journal of Organic Chemistry, 62(23), 8237-8239 (1997)
Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane.
Torimoto T, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 103(1), 153-157 (1997)
Dipyridine-chromium (VI) oxide oxidation of alcohols in dichloromethane.
Collins JC, et al.
Tetrahedron Letters, 9(30), 3363-3366 (1968)

Artículos

Greener Chemistry: Methods and Products for Amide Bond Formation

Amide bonds are ubiquitous in both nature and industrial applications. They are vital to the structure and function of biological macromolecules and polymers. The importance of this functionality has resulted in numerous approaches to its formation, ranging from stoichiometric activation of carboxylic acids to more recent advances in catalytic amide bond formation.

Solvent Miscibility Table

Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.

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