Merck
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439207

Sigma-Aldrich

2-Propanol

suitable for HPLC, 99.5%

Sinónimos:
IPA, Isopropanol, sec-Propyl alcohol, Isopropyl alcohol
Fórmula lineal:
(CH3)2CHOH
Número de CAS:
Peso molecular:
60.10
Beilstein:
635639
Número de EC:
Número MDL:
ID de la sustancia en PubChem:
NACRES:
NA.05

Nivel de calidad

100

densidad de vapor

2.1 (vs air)

presión de vapor

33 mmHg ( 20 °C)
44 mmHg ( 25 °C)

ensayo

99.5%

formulario

liquid

temp. de autoignición

750 °F

lim. expl.

2.0-12.7 %, 93 °C

technique(s)

HPLC: suitable

impurezas

≤0.05% water

residuo de evap.

<0.0003%

índice de refracción

n20/D 1.377 (lit.)

pH

7.0 (20 °C)

bp

82 °C (lit.)

mp

−89.5 °C (lit.)

solubilidad

water: soluble

densidad

0.785 g/mL at 25 °C (lit.)

λ

H2O reference

Absorción UV

λ: 205 nm Amax: 1.0
λ: 220 nm Amax: 0.30
λ: 230 nm Amax: 0.15
λ: 245 nm Amax: 0.05
λ: 260 nm Amax: 0.03
λ: 300-400 nm Amax: 0.01

application(s)

food and beverages

SMILES string

CC(C)O

InChI

1S/C3H8O/c1-3(2)4/h3-4H,1-2H3

InChI key

KFZMGEQAYNKOFK-UHFFFAOYSA-N

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Descripción general

2-Propanol (i-PrOH), a renewable secondary alcohol, is water soluble, colorless, volatile liquid with a sweet odor. It is a potential substitute to petroleum-derived gasoline. Preparation of methyl isobutyl ketone (MIBK) using 2-propanol as the precursor has been reported with yield as high as 25%. Solubility of benzoic acid has been investigated in 2-propanol by gravimetric method in the temperature range, 277-346K. Its photocatalytic degradation has been examined by various methods.

Aplicación

2-Propanol may be used in the following processes:
  • As a solvent in the synthesis of di- and trisubstituted ortho biaryls by Suzuki-Miyaura cross-coupling reaction.
  • As an alternate solvent to benzene in the analysis of total carbonyl compounds in heated and frying oils.
  • As a reaction medium in the preparation of cyclic ureas by reacting CO2 with diamines in the presence of pure cerium oxide (CeO2).

Envase

20 L in Nowpak™
4×4 L in PVC-coated bottle
18 L in VerSA-Flow™

pictogramas

FlameExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

3 - Flammable liquids

WGK

WGK 1

Punto de inflamabilidad F

53.6 °F - closed cup

Punto de inflamabilidad C

12.0 °C - closed cup

Certificado de Análisis

Introduzca el número de lote para buscar un certificado de análisis (COA).

Certificado de origen

Introduzca el número de lote para buscar un Certificado de origen (COO).

A general method for the Suzuki-Miyaura cross-coupling of sterically hindered aryl chlorides: Synthesis of di-and tri-ortho-substituted biaryls in 2-propanol at room temperature.
Navarro O, et al.
Journal of the American Chemical Society, 125(52), 16194-16195 (2003)
A modified method for the estimation of total carbonyl compounds in heated and frying oils using 2-propanol as a solvent.
Endo Y, et al.
Journal of the American Oil Chemists' Society, 78(10), 1021-1024 (2001)
Photocatalytic degradation of 2-propanol under irradiation of visible light by nanocrystalline titanium (IV) oxide modified with rhodium ion using adsorption method.
Kitano S, et al.
Chemistry Letters (Jpn), 39(6), 627-629 (2010)
Photocatalytic degradation of 2-propanol and phenol using Au loaded MnWO4 nanorod under visible light irradiation.
Chakraborty AK, et al.
Journal of Cluster Science, 23(2), 437-448 (2012)
Highly efficient synthesis of cyclic ureas from CO2 and diamines by a pure CeO2 catalyst using a 2-propanol solvent.
Tamura M, et al.
Green Chemistry, 15(6), 1567-1577 (2013)

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