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ALD00610

Sigma-Aldrich

2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile

≥95%

Empirical Formula (Hill Notation):
C11H7ClN4O
CAS Number:
Molecular Weight:
246.65

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

mp

156-159 °C

storage temp.

−20°C

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This Item
74104PH008260CBR01378
assay

≥95%

assay

≥96.0% (calc. on dry substance, AT)

assay

-

assay

-

form

powder

form

powder

form

-

form

solid

reaction suitability

reagent type: catalyst
reaction type: C-H Activation

reaction suitability

-

reaction suitability

-

reaction suitability

-

mp

156-159 °C

mp

-

mp

-

mp

-

storage temp.

−20°C

storage temp.

−20°C

storage temp.

-

storage temp.

-

Application

2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile is a bifunctional C-H activation template developed in the Yu lab for the conversion of phenols to 1,3-disubstituted arenes. The template is used for a one-pot Pd-catalyzed meta-selective C-H olefination of phenols followed by a nickel-catalyzed ipso-C-O activation and arylation.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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