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31733

Supelco

Emamectin benzoate

PESTANAL®, analytical standard

Synonym(s):
(4′’R)-4″-Deoxy-4″-(methylamino)avermectin B1 benzoate
CAS Number:
MDL number:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

form

neat

shelf life

limited shelf life, expiry date on the label

application(s)

HPLC: suitable
gas chromatography (GC): suitable

format

neat

InChI

1S/C49H75NO13.C7H6O2/c1-12-26(2)44-29(5)18-19-48(63-44)24-35-21-34(62-48)17-16-28(4)43(27(3)14-13-15-33-25-56-46-42(51)30(6)20-36(47(52)59-35)49(33,46)53)60-40-23-38(55-11)45(32(8)58-40)61-39-22-37(54-10)41(50-9)31(7)57-39;8-7(9)6-4-2-1-3-5-6/h13-16,18-20,26-27,29,31-32,34-46,50-51,53H,12,17,21-25H2,1-11H3;1-5H,(H,8,9)/b14-13+,28-16+,33-15+;/t26-,27-,29-,31-,32-,34+,35-,36-,37-,38-,39-,40-,41-,42+,43-,44+,45-,46+,48+,49+;/m0./s1

InChI key

GCKZANITAMOIAR-XWVCPFKXSA-N

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General description

Emamectin benzoate is a macrocyclic insecticide found to be stable aqueous hydrolysis. Avermectin B1 can be the starting material synthesizing emamectin benzoate. In some occasions, it is used as acaricide for vegetables, fruits and cereals.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Emamectin benzoate may be used as pesticide standard in supercritical fluid chromatography/tandem mass spectrometry (SFC/MS/MS) method for pesticide residue determination from brown rice, onion, and spinach samples.

Legal Information

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all

WGK Germany

WGK 3

Flash Point F

Not applicable

Flash Point C

Not applicable

Certificate of Analysis

Certificate of Origin

Terence Robert Roberts, David Herd Hutson
Metabolic Pathways of Agrochemicals: Herbicides and plant growth regulators;, 89-89 (2007)
Development of an enzyme-linked immunosorbent assay for residue analysis of the insecticide emamectin benzoate in agricultural products.
Ishibashi M
Journal of Chromatography A, 1266, 143-148 (2012)
Roy Beryl Julinta et al.
Environmental toxicology and pharmacology, 75, 103348-103348 (2020-02-08)
Emamectin benzoate (EB) premix top-coated onto feed is extensively used to treat ectoparasitic crustacean infestations in aquaculture. This study evaluated the safety of EB-dosing in Nile tilapia Oreochromis niloticus at the recommended dose and dosage of 50 μg/kg biomass/day for 7...
Development of an enzyme-linked immunosorbent assay for residue analysis of the insecticide emamectin benzoate in agricultural products.
Kondo M
Journal of Agricultural and Food Chemistry, 57(2), 359-364 (2009)

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